%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3cooch3-h-ts_6311+Gd_new

-1 1
 C                 -1.69330700   -0.03661500   -0.00998100
 H                 -3.35271200   -0.37333000    0.11848800
 H                 -1.62384300   -0.03236400    1.06327100
 H                 -1.93206900    0.87143100   -0.53346300
 H                 -1.56101900   -0.95891100   -0.54502200
 C                  0.36442200    0.41272800   -0.14467300
 O                  0.90222200    1.51355600   -0.24947700
 O                  1.17646100   -0.70265100    0.02327400
 C                  2.61500300   -0.50508200    0.06245200
 H                  2.89234000    0.14739700    0.89241700
 H                  3.04965100   -1.49294700    0.20451700
 H                  2.97071600   -0.07240400   -0.87440200

