%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3pcl3-cooch3-ts_6311+Gd1sp_new

0 1
 C                  0.86551200    0.00086600   -0.01238100
 H                  0.95910600    0.01400000   -1.08912200
 H                  0.95659700    0.92709800    0.53746900
 H                  0.95699200   -0.93866600    0.51424000
 P                 -1.31356000   -0.00000800   -0.00560700
 Cl                -2.17992900    1.68030700   -0.83836700
 Cl                -2.13969900   -0.10761000    1.88314700
 Cl                -2.18076600   -1.57343100   -1.02409600
 C                  3.42550220   -0.00204765   -0.00592342
 O                  4.41370613    0.51701690   -0.89974946
 O                  3.76203206   -0.57949724    0.99072076
 C                  5.71760523    0.22344311   -0.39125997
 H                  5.83641034   -0.83641825   -0.30477737
 H                  6.45703031    0.61183469   -1.06006677
 H                  5.83501942    0.67524592    0.57154226

