%mem=3000MB
%nprocshared=12
#p opt=(calcfc,ts,noeigentest,maxstep=4) freq b3lyp/6-311+g(d)
scrf=(smd,solvent=water) nosymm empiricaldispersion=gd3

ch3cooch3-sime3-ts_6311+Gd_new

-1 1
 C                  0.80274400    0.00118100    0.45969900
 H                  0.54565300   -1.03270400    0.29123900
 H                  0.44147200    0.70938500   -0.26989300
 H                  0.78897800    0.33154700    1.48673300
 Si                -2.23846300   -0.00209400    0.30653600
 C                 -2.10742200   -1.22812300   -1.18930200
 H                 -1.21552200   -1.02877500   -1.79678300
 H                 -2.03864800   -2.27242200   -0.85867000
 H                 -2.97984200   -1.15477700   -1.85696600
 C                 -4.02390000   -0.42031400    0.94592300
 H                 -4.07604100   -1.42264400    1.38916100
 H                 -4.36019100    0.28536000    1.71580300
 H                 -4.75966300   -0.38628400    0.12704000
 C                 -2.58559100    1.65340700   -0.64259600
 H                 -2.84029900    2.47363300    0.04045700
 H                 -1.71109100    1.98128600   -1.21904800
 H                 -3.42188500    1.54744300   -1.35115600
 C                  2.98430304   -0.00110631    0.01885027
 O                  3.32085387    1.15073153    0.02061888
 O                  3.97248815   -1.03473262    0.01623600
 C                  5.27639795   -0.44760466    0.01623600
 H                  6.01580972   -1.22101931    0.01623613
 H                  5.39451797    0.15876234   -0.85741537
 H                  5.39451852    0.15876237    0.88988728

