%nprocshared=20
%mem=41GB
%chk=Me-TS10-12.chk
#p opt=(maxstep=5,loose,modredundant) B3LYP genecp SCRF=(PCM,Solvent=Dichloromethane) EmpiricalDispersion=GD3  nosymm scf=(xqc,maxcyc=512)

preopt freq loose

1 1
 C                  1.68136565   -2.36351123    0.21666986
 C                  0.34771558   -1.90820864    0.27107763
 C                 -0.67541664   -2.87075699    0.13351091
 C                  0.92953794   -4.64951765   -0.16398222
 H                 -1.71056043   -2.53844624    0.17251954
 H                  1.16278248   -5.69672891   -0.33814559
 C                  0.05632245   -0.45850860    0.33773474
 C                  1.07308716    0.44287837    0.53483384
 C                  2.83202396   -1.41438296    0.45306306
 H                  3.42945874   -1.85023351    1.26414711
 H                  3.50310542   -1.42477121   -0.42161902
 C                  3.47923650    0.80143231    1.49485384
 C                  3.28793214    2.07188963    2.29433628
 H                  4.12890725    2.76206924    2.15316715
 H                  3.27674028    1.81353986    3.36570920
 H                  2.37109574    2.61919136    2.09750982
 C                  4.89037576    0.26090560    1.60978974
 H                  4.98896549   -0.45031475    2.44660232
 H                  5.60300324    1.07092290    1.79999702
 H                  5.22041161   -0.26432860    0.70726402
 P                 -4.11999831    0.93515103   -0.29279178
 C                 -4.89035527    1.85262089    1.10412793
 H                 -5.90535829    2.17246248    0.84551414
 H                 -4.28222464    2.73107492    1.33968201
 H                 -4.92588448    1.20818175    1.98737530
 C                 -4.28900366    2.09020147   -1.71543527
 H                 -5.33198914    2.40015582   -1.84075384
 H                 -3.94503064    1.59541136   -2.62854989
 H                 -3.66607113    2.97268482   -1.54237402
 C                 -5.33339468   -0.39741972   -0.66359993
 H                 -5.37980051   -1.09188452    0.18045654
 H                 -5.00812479   -0.94928554   -1.55039474
 H                 -6.32831796    0.02404230   -0.84241163
 Au                -1.92120799    0.18085561    0.11412301
 C                 -0.39737858   -4.22085311   -0.07113366
 H                 -1.21329473   -4.93232547   -0.17267404
 C                  1.95577232   -3.71424106   -0.01981786
 H                  2.99391137   -4.03909043   -0.07297938
 C                  0.78232079    1.92905108    0.33779185
 H                  0.38196438    2.41056013    1.23997155
 H                  1.67220234    2.47930171    0.02426801
 H                  0.03401659    2.05781631   -0.45027131
 C                  2.45664957    0.01762226    0.84131281
 H                  2.99443923    0.18554216   -0.35628372
 O                  3.54350615    0.35698328   -1.57899343
 H                  4.33899834    0.95028320   -1.41243527
 C                  3.96979284   -0.86046383   -2.22812458
 O                  5.62910399    1.85191124   -0.95783593
 H                  4.76137965   -1.35917901   -1.66070759
 H                  3.09608131   -1.50983324   -2.29559079
 H                  4.32399201   -0.61944237   -3.23410951
 H                  6.46924363    1.46545117   -1.25454903
 C                  5.58677305    3.23437284   -1.35762885
 H                  4.66288228    3.64485089   -0.94789477
 H                  6.43817631    3.78072809   -0.93927042
 H                  5.57928279    3.33691452   -2.44865585

43 44 F
44 45 F

C H P O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD


--link1--
%nproc=20
%Mem=41GB
%Chk=Me-TS10-12.chk
#p opt=(ts,noeigentest,calcfc,modredundant,maxstep=9) freq=noraman geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP genecp EmpiricalDispersion=GD3 nosymm scf=(xqc,maxcyc=512) gfinput gfprint

opt freq

1 1

43 44 A
44 45 A

C H P O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD










