%nprocshared=20
%mem=41GB
%chk=Cl-TS1-2-6endo
#p opt=(maxstep=17,modredundant) B3LYP genecp SCRF=(PCM,Solvent=Dichloromethane) EmpiricalDispersion=GD3  nosymm scf(xqc,maxcyc=512)

opt freq

1 1
 C                 -1.20133025   -1.26877360   -0.20532744
 C                 -0.90981456   -0.03386314   -0.09937987
 C                 -1.61881540    1.24181014   -0.07614648
 C                 -2.85748448    1.37162664   -0.74630863
 C                 -1.07437230    2.33936939    0.61442813
 H                 -0.12647118    2.22069318    1.13140148
 C                 -2.95926888    3.69838032   -0.02189143
 H                 -3.48568791    4.64824290   -0.01021211
 C                 -3.47099162    0.22097954   -1.51656987
 H                 -2.87524165    0.05670959   -2.42468591
 H                 -4.46666649    0.52015512   -1.86911720
 C                 -3.58584545   -1.11710557   -0.81334939
 H                 -3.51886129   -1.96984660   -1.48625246
 C                 -3.91473197   -1.38479793    0.47907301
 C                 -4.09076109   -2.80916406    0.93476202
 H                 -3.42688826   -3.02880432    1.78160825
 H                 -3.89263969   -3.53295026    0.14013559
 H                 -5.11724321   -2.96228517    1.29332903
 C                 -4.13445009   -0.34955498    1.55107555
 H                 -4.98704977   -0.63777027    2.17675459
 H                 -4.31347397    0.65055052    1.15660284
 H                 -3.25924726   -0.29939765    2.21286801
 Au                 1.26113070   -0.09633697   -0.02184757
 P                  3.56879335    0.11609342    0.06214023
 C                  4.09526532    1.64254825    0.92933980
 H                  3.68022041    2.51377258    0.41502776
 H                  5.18781949    1.71011352    0.93968176
 H                  3.72049263    1.62554411    1.95646179
 C                  4.35371709    0.19936189   -1.59205905
 H                  4.12958568   -0.71456786   -2.14889875
 H                  5.43811817    0.30656630   -1.48613406
 H                  3.95354851    1.05595537   -2.14123999
 C                  4.41123223   -1.25824472    0.93547144
 H                  4.03480679   -1.32458010    1.95973388
 H                  5.49148127   -1.08043670    0.95347611
 H                  4.20413025   -2.19997614    0.41976813
 C                 -1.74326337    3.55935211    0.65120695
 H                 -1.31603915    4.39530742    1.19652617
 C                 -3.50282854    2.61251032   -0.71029666
 H                 -4.45251750    2.72483035   -1.22698359
 Cl                -0.85534950   -2.98795379   -0.35471559

1 12 F
1 14 F

C H P Cl 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD


--link1--
%nproc=20
%Mem=41GB
%Chk=Cl-TS1-2-6endo
#p opt=(ts,noeigentest,calcfc,modredundant,maxstep=9) freq=noraman geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP genecp EmpiricalDispersion=GD3 nosymm scf(xqc,maxcyc=512) gfinput gfprint

opt freq

1 1

1 12 A
1 14 A

C H P Cl 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD




