%nprocshared=20
%mem=41GB
%chk=Ph-TS2b-8transoid.chk
#p opt=(maxstep=17,modredundant) B3LYP genecp SCRF=(PCM,Solvent=Dichloromethane) EmpiricalDispersion=GD3  nosymm scf(xqc,maxcyc=512)

opt freq

1 1
 C                 -0.82804608   -0.38938818   -0.17241298
 C                  0.09551458    0.60239535   -0.06969957
 C                 -0.35835051    2.01891890   -0.03582718
 C                 -1.64227250    2.37451427   -0.51244563
 C                  0.45801705    3.04262084    0.47864167
 H                  1.44180836    2.78483780    0.86327065
 C                 -1.23157222    4.70894846    0.02386136
 H                 -1.57293989    5.74026502    0.04301600
 C                 -2.54103035    1.28133870   -1.03488591
 H                 -2.30263333    1.08852623   -2.09120480
 H                 -3.59350387    1.58006462   -0.99909220
 C                 -2.33911449   -0.04873683   -0.29594965
 H                 -2.81012595   -0.84784528   -0.87976611
 C                 -2.86478298   -0.13992764    1.10736920
 C                 -3.49032781   -1.30876561    1.53294382
 H                 -3.57842841   -1.49252101    2.60496339
 H                 -3.41748290   -2.19891319    0.90744882
 C                 -2.78551915    1.02817759    2.03632020
 H                 -3.16058576    0.77945292    3.03136445
 H                 -3.36033671    1.86969101    1.63146867
 H                 -1.75142314    1.37894748    2.11172768
 Au                 2.14687020    0.21012819   -0.03469427
 P                  4.46977158   -0.18034851   -0.01036375
 C                  5.38669375    0.86599813    1.19193461
 H                  5.22627689    1.92071521    0.95008647
 H                  6.45838657    0.64419678    1.15731882
 H                  5.00904936    0.67780075    2.20119995
 C                  5.31339942    0.13978466   -1.61243263
 H                  4.89419823   -0.51506125   -2.38186397
 H                  6.38971776   -0.04319229   -1.52621581
 H                  5.14437972    1.17915660   -1.90861129
 C                  4.96331202   -1.89766074    0.42286829
 H                  4.56860734   -2.15054277    1.41120796
 H                  6.05411112   -1.99471769    0.43196202
 H                  4.54339565   -2.59336423   -0.30948401
 C                  0.02971990    4.37104645    0.51614908
 H                  0.68181838    5.13754778    0.92619676
 C                 -2.06052345    3.70458762   -0.48621359
 H                 -3.05123609    3.95698731   -0.85868344
 H                 -4.73829593   -0.89655053    1.27778849
 O                 -6.01839100   -0.62085756    1.09339182
 H                 -6.04653094   -0.06319226    0.25459553
 C                 -6.79402415   -1.82506395    0.89548330
 O                 -5.89267015    0.76215708   -1.13680407
 H                 -6.40227809   -2.41667793    0.06148106
 H                 -6.73271321   -2.40163994    1.81920962
 H                 -7.83322802   -1.54815134    0.70332220
 H                 -6.58243909    1.42979429   -1.28479403
 C                 -5.73869894   -0.03401312   -2.32625838
 H                 -4.96834331   -0.77458046   -2.10336862
 H                 -6.67039923   -0.54754763   -2.58779352
 H                 -5.40700929    0.58729581   -3.16397107
 C                 -0.51807197   -1.89767586   -0.19658575
 C                 -0.39881094   -2.56581752   -1.41553404
 C                 -0.35643694   -2.59580722    1.00009084
 C                 -0.11864448   -3.93192050   -1.43769565
 H                 -0.52705810   -2.01529592   -2.35878397
 C                 -0.07520646   -3.96212888    0.97808109
 H                 -0.45022354   -2.06932741    1.96089888
 C                  0.04357101   -4.63027310   -0.24052969
 H                 -0.02524804   -4.45875276   -2.39843568
 H                  0.05259128   -4.51223099    1.92175986
 H                  0.26452560   -5.70738091   -0.25825411

15 40 F
40 41 F

C H P O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD


--link1--
%nproc=20
%Mem=41GB
%chk=Ph-TS2b-8transoid.chk
#p opt=(ts,noeigentest,calcfc,modredundant,maxstep=9) freq=noraman geom=checkpoint guess=read SCRF=(PCM,Solvent=Dichloromethane) B3LYP genecp EmpiricalDispersion=GD3 nosymm scf(xqc,maxcyc=512) gfinput gfprint

opt freq

1 1

15 40 A
40 41 A

C H P O 0
6-31G*
****
Au 0
SDD 
****

Au 0
SDD









