%nprocshared=20
%mem=41GB
#p b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

single point

1 1
 C                  1.15739300    2.50645500    1.16064100
 C                  0.87868500    1.14436500    0.92639100
 C                  1.80426400    0.18283200    1.34469800
 C                  3.26545700    1.95352700    2.16232900
 H                  1.60856400   -0.87722300    1.21824300
 H                  4.19253800    2.25250500    2.64289800
 C                 -0.46155900    1.04611200    0.26244400
 C                 -0.93856300   -0.14382700   -0.24725000
 C                  0.04459700    3.29993600    0.60975600
 H                 -0.17324500    4.30971800    0.95301600
 C                 -0.98101200    2.41753000    0.19953200
 C                 -3.34318100    2.68693700    0.88925400
 H                 -3.08162200    3.29880800    1.75951700
 H                 -4.34131200    2.97929000    0.54705300
 H                 -3.37789300    1.63908000    1.19857700
 C                 -2.31716800    4.39408200   -0.68279400
 H                 -3.30358700    4.65284800   -1.08033100
 H                 -2.11664300    5.06682700    0.15842000
 H                 -1.57535500    4.58433100   -1.46579800
 P                  1.07219700   -4.04317000   -0.73852100
 C                 -0.00080400   -5.49418100   -0.40234000
 H                  0.56016900   -6.42402400   -0.54150200
 H                 -0.37057300   -5.44215900    0.62557500
 H                 -0.85552500   -5.47863300   -1.08429500
 C                  2.52710400   -4.26668000    0.35881900
 H                  3.00294100   -5.23454100    0.17008600
 H                  3.24704200   -3.46436500    0.17398400
 H                  2.20531400   -4.21633500    1.40294000
 C                  1.71852100   -4.31459800   -2.43519500
 H                  0.89102000   -4.27999000   -3.14937400
 H                  2.43051100   -3.52255700   -2.68379000
 H                  2.21758200   -5.28690500   -2.50126800
 Au                 0.00812100   -1.97648600   -0.45131900
 C                  2.99202200    0.59511400    1.95587600
 H                  3.70758600   -0.15364700    2.28393800
 C                  2.34267600    2.92332400    1.76282700
 H                  2.53780200    3.98021300    1.92493100
 Br                -2.73788800   -0.25973000   -0.99628000
 C                 -2.32145400    2.91728300   -0.25436800
 H                 -2.64334500    2.32347600   -1.11338600
 H                  0.46037100    3.55816500   -0.62193800
 O                  0.99909400    3.84813500   -1.80826900
 H                  1.19732300    4.83736300   -1.78616500
 C                  2.23320900    3.11710800   -2.00311600
 O                  1.53389600    6.40819500   -1.58557600
 H                  2.95566500    3.35214600   -1.21623300
 H                  1.98508600    2.05555500   -1.96743800
 H                  2.64306500    3.36972600   -2.98426300
 H                  0.99230500    6.95708700   -2.17646300
 C                  1.32408200    6.84028700   -0.22921300
 H                  1.95404900    6.20638100    0.39843000
 H                  1.63013600    7.88395500   -0.10511000
 H                  0.27621900    6.72630700    0.07345000

-C -H -P -O 0
6-311+G(d,p)
****
Au 0
SDD
****
Br 0
LANL2DZ
D 1 1.0
0.428 1.0
****

Au 0
SDD
Br 0
LANL2DZ




