%nprocshared=20
%mem=41GB
#p b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

single point

1 1
 C                  2.73900900    1.81190700   -1.37477500
 C                  1.78923400    0.90817800   -0.86771600
 C                  2.03783800   -0.47007800   -0.95080300
 C                  4.15007700   -0.01113800   -2.06430200
 H                  1.32743500   -1.18314200   -0.54342500
 H                  5.06524000   -0.37525000   -2.52206400
 C                  0.65580400    1.64479300   -0.26804600
 C                 -0.49261200    1.11176100    0.19954800
 C                  2.32359500    3.24405600   -1.16409600
 H                  2.07703500    3.74771400   -2.10458900
 H                  3.12110100    3.82351400   -0.68733000
 C                  1.02530500    3.13084900   -0.27272500
 H                  0.22836300    3.73662500   -0.71409600
 C                  1.33543100    3.70942500    1.07729300
 C                  1.79282700    2.91550400    2.12921900
 H                  1.86697400    3.37866400    3.11308300
 H                  1.49369900    1.86705900    2.12303000
 C                  1.27796800    5.19077500    1.19651800
 H                  0.21420100    5.44881100    1.31291500
 H                  1.81759600    5.56918500    2.06698300
 H                  1.62343700    5.68935400    0.28513400
 P                 -2.03477100   -3.01141200    0.31656900
 C                 -3.14019800   -3.37623600    1.73753000
 H                 -3.49265400   -4.41186500    1.69022100
 H                 -2.59606900   -3.21862800    2.67309700
 H                 -3.99834200   -2.69861500    1.71271000
 C                 -0.72087800   -4.29171800    0.41191500
 H                 -1.16207900   -5.29337900    0.43914400
 H                 -0.06894400   -4.20615900   -0.46217900
 H                 -0.12185500   -4.13339800    1.31324100
 C                 -3.02046800   -3.47881000   -1.16143200
 H                 -3.87944500   -2.80811100   -1.25336200
 H                 -2.40117800   -3.37930700   -2.05752700
 H                 -3.37272000   -4.51195200   -1.07422100
 Au                -1.21359200   -0.81800200    0.26274500
 C                  3.21556400   -0.91975000   -1.54857700
 H                  3.41220500   -1.98670300   -1.60730800
 C                  3.91346200    1.36283500   -1.97487400
 H                  4.64056600    2.07423300   -2.35729800
 Br                -1.75789900    2.44012400    0.99950100
 H                  3.00595200    2.81190300    1.75346800
 O                  4.35325300    2.57954300    1.39182500
 H                  4.92576400    3.11004500    2.02203400
 C                  4.73068100    1.17023000    1.49683500
 O                  5.80032500    3.96698300    3.15535100
 H                  4.00656500    0.65180900    0.86421600
 H                  6.67281600    4.22307700    2.80764400
 C                  5.09809400    5.17640100    3.55177800
 H                  4.13794400    4.80236100    3.92321400
 C                  4.61392600    0.69720500    2.94273600
 H                  4.88072900   -0.36244300    3.01466200
 H                  5.28898700    1.26956300    3.58880800
 H                  3.59148000    0.81793100    3.31574500
 C                  6.12972200    1.00389000    0.91699700
 H                  6.40142400   -0.05678900    0.89328600
 H                  6.16568200    1.39432100   -0.10334900
 H                  6.86980700    1.53296600    1.52929800
 C                  5.85059200    5.86563500    4.68389900
 H                  6.83143500    6.21348500    4.33602600
 H                  5.29061200    6.73602400    5.04194500
 H                  6.00156200    5.17639500    5.52014500
 C                  4.87053800    6.07808900    2.34119200
 H                  4.38000100    5.52784400    1.53147500
 H                  4.24259200    6.93448100    2.60940200
 H                  5.82568000    6.46350800    1.96366100

-C -H -P -O 0
6-311+G(d,p)
****
Au 0
SDD
****
Br 0
LANL2DZ
D 1 1.0
0.428 1.0
****

Au 0
SDD
Br 0
LANL2DZ




