%nprocshared=20
%mem=41GB
#p b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

single point

1 1
 C                  2.63463800    1.77462200   -0.03309300
 C                  1.97977000    0.58560400    0.33430800
 C                  2.71990000   -0.59338500    0.48833300
 C                  4.73576800    0.60969200   -0.14385000
 H                  2.23509700   -1.51138000    0.80604600
 H                  5.80710900    0.61162200   -0.32330200
 C                  0.52807400    0.84373000    0.49613300
 C                 -0.44271700   -0.09346600    0.41438100
 C                  1.67030100    2.93267800   -0.13122800
 H                  1.43932000    3.16711500   -1.17583200
 H                  2.05326600    3.84534000    0.32961000
 C                 -0.58287900    2.23441500    2.93146000
 H                 -0.45944200    2.76288000    3.88090700
 H                 -1.66749000    2.17655000    2.73341800
 H                 -0.22228000    1.20375700    2.97667400
 C                  0.10086400    4.45882400    1.95051600
 H                 -0.73818900    4.85138700    2.53402800
 H                  1.00946900    4.66164000    2.54326600
 H                  0.19397500    4.98045200    0.99619300
 P                 -0.21477000   -4.45118800   -0.20132100
 C                 -1.14087000   -5.44592800    1.03432700
 H                 -1.03521700   -6.51468900    0.82126400
 H                 -0.75178600   -5.23421600    2.03436600
 H                 -2.19907400   -5.17115900    1.00425200
 C                  1.49516200   -5.11876300   -0.13927700
 H                  1.48815900   -6.19998800   -0.31180800
 H                  2.10334200   -4.63101500   -0.90637900
 H                  1.93249700   -4.90935400    0.84106300
 C                 -0.86321000   -5.01144400   -1.82621400
 H                 -1.91777800   -4.73503000   -1.91248700
 H                 -0.30492500   -4.52100400   -2.62872500
 H                 -0.76116200   -6.09733900   -1.92323900
 Au                -0.33479200   -2.13789100    0.13916200
 C                  4.09485100   -0.57306000    0.24642400
 H                  4.67412000   -1.48343700    0.37359300
 C                  4.00388000    1.79307200   -0.28443300
 H                  4.49815300    2.71654200   -0.57466300
 Br                -2.32405700    0.55609200    0.48652000
 C                  0.01236900    2.98674700    1.81622900
 C                  0.39941600    2.36101800    0.57915800
 H                 -0.51241200    2.73894400   -0.04035200
 O                 -1.48686400    3.61403200   -1.14277400
 H                 -0.86624800    4.35644100   -1.34552000
 C                 -1.88337100    2.97066400   -2.37348900
 O                  0.18325500    5.75940500   -1.27886700
 H                 -2.71615000    2.32226100   -2.08419800
 H                  0.91942900    5.75013200   -1.91323400
 C                 -0.58449700    6.98000100   -1.47043700
 H                 -1.02478800    6.95359800   -2.47734900
 C                 -2.36835400    4.02297700   -3.36874900
 H                 -1.54329600    4.68634700   -3.65853600
 H                 -2.75418800    3.54786100   -4.27700600
 H                 -3.16363900    4.63203600   -2.92722100
 C                 -0.74947500    2.10886800   -2.92775500
 H                 -0.43338700    1.36618600   -2.18805300
 H                 -1.07416600    1.57939600   -3.83049600
 H                  0.11470100    2.73119900   -3.19322700
 C                 -1.69844600    6.95130400   -0.43282300
 H                 -1.28125600    7.01981500    0.57829600
 H                 -2.37401600    7.79874400   -0.58510400
 H                 -2.27417000    6.02423200   -0.51099200
 C                  0.32538300    8.19553800   -1.33580200
 H                  1.12242900    8.18014900   -2.08861600
 H                 -0.24867800    9.11815900   -1.47333600
 H                  0.78499600    8.21477800   -0.34131600

-C -H -P -O 0
6-311+G(d,p)
****
Au 0
SDD
****
Br 0
LANL2DZ
D 1 1.0
0.428 1.0
****

Au 0
SDD
Br 0
LANL2DZ




