%nprocshared=20
%mem=41GB
#p b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

single point

0 1
 C                 -1.09975700    0.79879600   -0.04604700
 H                 -2.20285200    0.78331200   -0.04891000
 O                 -0.63210900    1.45428200    1.14081800
 H                 -0.93702700    2.37504200    1.10552400
 C                 -0.58968900   -0.63574400    0.02809500
 H                 -0.94758400   -1.21755300   -0.82792900
 H                  0.50667300   -0.64678600    0.02382800
 H                 -0.93582600   -1.11839000    0.94810400
 C                 -0.61356800    1.52464200   -1.30180700
 H                 -0.96697400    1.02084700   -2.20893600
 H                 -0.98360000    2.55745500   -1.32461900
 H                  0.48223200    1.55181400   -1.32055700

-C -H -P -O 0
6-311+G(d,p)
****