%nprocshared=20
%mem=41GB
#p b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

single point

1 1
 C                  3.07169800    0.65694400   -0.85516100
 C                  2.03702100    0.10811400   -0.08283000
 C                  2.01969800   -1.26161900    0.19967100
 C                  4.03621300   -1.52068700   -1.13752800
 H                  1.25902800   -1.69505200    0.84104900
 H                  4.80992800   -2.16453500   -1.54530500
 C                  1.14881900    1.21442100    0.37887500
 C                 -0.11826300    0.96446200    0.94953000
 C                  2.88492500    2.14239100   -0.94534100
 H                  2.69793400    2.48631900   -1.97274800
 H                  3.75172300    2.72404600   -0.59842100
 C                  1.68647700    2.43268500   -0.08587900
 C                  1.95368000    4.38921800    1.38661200
 H                  3.03685700    4.42972000    1.23154500
 H                  1.59321000    5.40464700    1.57947600
 H                  1.74719000    3.77270900    2.26503100
 C                  1.50662900    4.75320700   -1.09067400
 H                  1.10305100    5.74881000   -0.88256300
 H                  2.57803200    4.86338000   -1.28791700
 H                  1.02300400    4.37301400   -1.99651100
 P                 -2.62070100   -2.54624300    0.04580100
 C                 -3.91379900   -2.92825600    1.28901300
 H                 -4.47980200   -3.81425500    0.98377600
 H                 -3.44369900   -3.11257300    2.25905300
 H                 -4.59242600   -2.07577900    1.38204600
 C                 -1.64503900   -4.09064500   -0.12605200
 H                 -2.30408200   -4.92791700   -0.37684300
 H                 -0.90037800   -3.96162800   -0.91647100
 H                 -1.12818700   -4.30295500    0.81390800
 C                 -3.51732300   -2.37098600   -1.54530600
 H                 -4.18661500   -1.50776100   -1.49409500
 H                 -2.79630000   -2.21209500   -2.35200000
 H                 -4.10124200   -3.27397700   -1.75069900
 Au                -1.28569700   -0.68801100    0.57240200
 C                  3.02222000   -2.06999800   -0.34280000
 H                  3.02113000   -3.13541000   -0.13164000
 C                  4.07264100   -0.14523800   -1.39125200
 H                  4.87019600    0.28703800   -1.98879200
 Br                -0.90621500    2.26505800    2.09553300
 C                  1.23670400    3.84097400    0.11855400
 H(Iso=2.014)       0.16284800    3.85254200    0.32576400

-C -H -P -O 0
6-311+G(d,p)
****
Au 0
SDD
****
Br 0
LANL2DZ
D 1 1.0
0.428 1.0
****

Au 0
SDD
Br 0
LANL2DZ




