%nprocshared=20
%mem=41GB
#p b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=1024)

single point

1 1
 C                  0.55542800   -2.28194500   -0.53228900
 C                 -0.52819600   -1.47327300   -0.06430800
 C                 -1.73297500   -2.05295000    0.41796000
 C                 -0.74520200   -4.22194200   -0.02574300
 H                 -2.55229600   -1.43303500    0.76614200
 H                 -0.84611400   -5.30285900    0.00144000
 C                 -0.17088600   -0.12446600   -0.18314300
 C                  1.67832500   -1.41644300   -1.02682000
 H                  1.75456000   -1.49858400   -2.11839700
 H                  2.64647900   -1.70554300   -0.61176000
 C                  1.25261000    0.01614000   -0.61641100
 H                  1.34356800    0.73083100   -1.43975100
 C                  1.98262500    0.59846100    0.62090900
 C                  2.06581100   -0.10577600    1.75631400
 H                  2.59941200    0.28559300    2.61730200
 H                  1.63575500   -1.09802000    1.86212300
 C                  2.53610000    1.98662000    0.45474800
 H                  1.74462100    2.70730500    0.21006300
 H                  3.03644200    2.32767800    1.36499100
 H                  3.25196900    2.01577500   -0.37691900
 C                 -1.82625200   -3.42880200    0.42993500
 H                 -2.72590900   -3.91411400    0.79181400
 C                  0.44320700   -3.66428200   -0.50900000
 H                  1.25084100   -4.29973600   -0.85619300
 Br                -1.81766500    1.50170800   -1.70733700
 C                 -1.05242500    1.03497100    0.08111900
 H                 -0.51234400    1.91518400    0.42395200
 H                 -1.89436700    0.81277600    0.73323900

-C -H -P -O 0
6-311+G(d,p)
****
Br 0
LANL2DZ
D 1 1.0
0.428 1.0
****

Br 0
LANL2DZ



