%nprocshared=20
%mem=41GB
#p opt=maxstep=17 freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  2.15530077   -1.97965107    0.33452585
 C                  0.86011468   -1.64508072   -0.11869053
 C                  0.01475448   -2.69413108   -0.52552368
 C                  1.71134988   -4.33985939   -0.01071372
 H                 -0.98343797   -2.45632026   -0.88568871
 H                  2.04219273   -5.37393236    0.03315644
 C                  0.43099576   -0.22340080   -0.13856604
 C                  1.37414431    0.75896583   -0.19442543
 C                  3.04823219   -0.84178757    0.74722145
 H                  2.76276002   -0.49441311    1.75115629
 H                  4.08946730   -1.16935289    0.79647953
 C                  2.86503286    0.32453649   -0.24638515
 H                  3.03531901   -0.07456559   -1.26257318
 C                  3.93164766    1.42008620   -0.05459489
 C                  4.09228098    1.94481686    1.35711280
 H                  4.83793494    2.74179919    1.41322182
 H                  4.35007062    1.14979128    2.05968530
 H                  3.13222294    2.36255296    1.67085062
 C                  4.00325871    2.49161935   -1.12875058
 H                  4.97945606    2.98371916   -1.12587302
 H                  3.26408875    3.26653544   -0.92724794
 H                  3.80814999    2.08021586   -2.12348974
 P                 -3.93675581    0.56858870    0.12195212
 C                 -4.43981566    1.59431280    1.56321524
 H                 -5.52567745    1.73547247    1.57490041
 H                 -3.94753722    2.56954089    1.50689701
 H                 -4.12837042    1.09916689    2.48755094
 C                 -4.66070678    1.44768586   -1.32242264
 H                 -5.73648607    1.59787292   -1.18305772
 H                 -4.49083119    0.85921209   -2.22877345
 H                 -4.17074521    2.41871813   -1.43971398
 C                 -4.96406919   -0.94830057    0.27916472
 H                 -4.66881396   -1.49564001    1.17906158
 H                 -4.79950225   -1.59137301   -0.59028743
 H                 -6.02606048   -0.68843823    0.34311591
 Au                -1.62064628    0.16712420   -0.03652541
 C                  0.43379532   -4.02451064   -0.47988292
 H                 -0.23863350   -4.81369268   -0.80602141
 C                  2.56704443   -3.31158641    0.39427821
 H                  3.56714241   -3.54581931    0.75329028
 C                  0.99347439    2.21603044   -0.32312669
 H                 -0.08236981    2.33151718   -0.16756124
 H                  1.49811409    2.86771544    0.40022132
 H                  1.21952255    2.60676051   -1.32447964
 O                  5.19323369    0.60720317   -0.28843049
 C                  6.52822066    1.11656485    0.07725216
 H                  6.54958576    1.16444349    1.16204478
 H                  7.23705417    0.37553534   -0.28885240
 H                  6.69884300    2.09209938   -0.37725807

C H P O 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD




