%nprocshared=20
%mem=41GB
#p opt=(maxstep=17) freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  1.23011209   -1.46592263   -0.20632571
 C                  1.71594013   -0.29856154    0.28719605
 C                  0.89747647    0.99659623    0.13318579
 C                 -0.18481558    1.02430379   -0.74983370
 C                  1.23781235    2.14384930    0.86164143
 H                  2.08510770    2.13233259    1.51498511
 C                 -0.64655161    3.32004456   -0.12150203
 H                 -1.24542908    4.20260240   -0.20716082
 C                 -0.47697297   -0.21577894   -1.60936076
 H                  0.15181228   -0.17543169   -2.47417358
 H                 -1.50351871   -0.22345277   -1.91109731
 C                 -0.18519370   -1.50646764   -0.81697390
 H                 -0.27610898   -2.34048267   -1.48109238
 C                 -1.19703143   -1.64828990    0.33527211
 C                 -1.61945811   -3.04720868    0.82125767
 H                 -0.95942352   -3.36874527    1.59963327
 H                 -1.57176361   -3.73771898    0.00527927
 H                 -2.62069143   -3.00713781    1.19652578
 C                  0.46343644    3.30597982    0.73581742
 H                  0.71867009    4.18192687    1.29480985
 C                 -0.96963480    2.17835779   -0.86798653
 H                 -1.81146889    2.18951428   -1.52835833
 C                  2.07594440   -2.75043533   -0.12761836
 H                  2.71830461   -2.70270538    0.72677921
 H                  1.42932105   -3.59851204   -0.04076134
 H                  2.66789621   -2.84257466   -1.01418669
 H                  2.65841827   -0.28111240    0.79348696
 C                 -1.78644248   -0.39119339    1.00153255
 H                 -1.16508176   -0.09759225    1.82166012
 H                 -1.83211496    0.40337018    0.28635233
 H                 -2.77165656   -0.60592092    1.35950642

C H 0
6-31G*
****




