%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=9) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  1.96007604    2.91449181   -0.41236110
 C                  1.40920048    1.73962776    0.12301311
 C                  2.24133150    0.75784728    0.66268347
 C                  4.17057236    2.09870306    0.01635539
 H                  1.83272285   -0.12753113    1.13968068
 H                  5.24829321    2.22781918   -0.01776478
 C                 -0.08265115    1.85302429    0.05379335
 C                 -0.92794978    0.74131335   -0.08557935
 C                  0.85447149    3.88556509   -0.72201662
 H                  0.66612588    4.00127463   -1.80648308
 H                  1.02669844    4.89780092   -0.34302785
 C                 -0.37215720    3.22919676   -0.16638447
 H                 -2.30526552    3.66537910   -0.72343192
 C                 -1.63860997    3.96889908    0.10397935
 C                 -1.49956583    5.50094708    0.04442791
 H                 -1.11739527    5.84801061   -0.92017782
 H                 -2.48536646    5.95013641    0.19592526
 H                 -0.83952928    5.86707883    0.83771414
 C                 -2.33784876    3.54330719    1.43173276
 H                 -2.05549604    4.23735810    2.22844717
 H                 -3.42123285    3.58811800    1.30780544
 H                 -2.07106452    2.53583147    1.75362390
 P                  0.13311481   -3.55264788    0.01648432
 C                 -0.99128889   -4.57701713    1.04250510
 H                 -0.67005151   -5.62329539    1.01906331
 H                 -0.97729778   -4.21450166    2.07418961
 H                 -2.01076242   -4.49956050    0.65462748
 C                  1.81049183   -3.87938974    0.68362188
 H                  2.01448777   -4.95503050    0.68121007
 H                  2.55433185   -3.36484867    0.06886998
 H                  1.87506919   -3.49928771    1.70705756
 C                  0.11555707   -4.34555772   -1.63826172
 H                 -0.88606510   -4.26427022   -2.06952192
 H                  0.82519693   -3.83532999   -2.29547606
 H                  0.39166352   -5.40151798   -1.55311135
 Au                -0.42359267   -1.27119674   -0.03179502
 C                  3.62579720    0.95345032    0.60935104
 H                  4.28532751    0.20697037    1.04240637
 C                  3.33454015    3.09514989   -0.49957349
 H                  3.74953109    4.00447258   -0.92497513
 Cl                -2.59968366    1.03481379   -0.54563697

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD




