%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=9) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  1.99853946    2.86242319   -0.33568119
 C                  1.38194314    1.71090713    0.18493689
 C                  2.17572122    0.67198766    0.68147885
 C                  4.17039441    1.90909334    0.03981949
 H                  1.72286083   -0.20083252    1.14107128
 H                  5.25322648    1.97568999   -0.01389552
 C                 -0.10486892    1.85758760    0.09122287
 C                 -0.92684520    0.77748954   -0.01872118
 C                  0.95598981    3.89036191   -0.70202674
 H                  0.88708748    4.04220253   -1.78945701
 H                  1.16715418    4.87054136   -0.26085688
 C                 -0.34618737    3.30373910   -0.15490560
 C                 -2.48221150    3.73562116    1.15753636
 H                 -2.40074826    4.50321205    1.94145962
 H                 -3.51214032    3.76036202    0.78510998
 H                 -2.29319621    2.76450001    1.61520812
 C                 -1.35711264    5.59388432   -0.15700265
 H                 -2.35913926    6.03373456   -0.20493536
 H                 -0.83531097    6.07031946    0.68279381
 H                 -0.82489786    5.85811772   -1.07473052
 P                  0.11195562   -3.51130834   -0.03397527
 C                 -1.03836681   -4.59282433    0.90354338
 H                 -0.70835510   -5.63557554    0.85261095
 H                 -1.07100688   -4.27186137    1.94843893
 H                 -2.04256992   -4.50805818    0.47867162
 C                  1.76694679   -3.84706131    0.68770462
 H                  1.99579663   -4.91668029    0.64116795
 H                  2.52403151   -3.28800804    0.13022141
 H                  1.78334214   -3.51580977    1.73002110
 C                  0.18105653   -4.25412958   -1.71189275
 H                 -0.80017130   -4.17124084   -2.18772018
 H                  0.91281696   -3.71401891   -2.31907640
 H                  0.46776579   -5.30892125   -1.64830858
 Au                -0.44958295   -1.23756532   -0.01127513
 C                  3.56710720    0.77683428    0.60067772
 H                  4.18569241   -0.02663796    0.99101220
 C                  3.38248315    2.96774437   -0.42451246
 H                  3.84340685    3.86263711   -0.83405768
 C                 -1.44975314    4.08325351    0.08876604
 Cl                -2.66511432    1.03365541   -0.39941450

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



