%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=9) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  0.36911731    3.31618930    1.63351882
 C                  0.18160726    1.97509029    1.25729962
 C                 -0.13557251    1.02437378    2.23877449
 C                 -0.06619505    2.76479906    3.93506453
 H                 -0.29460760   -0.01468903    1.96692362
 H                 -0.16728712    3.06310555    4.97469407
 C                  0.34742878    1.82907062   -0.20659624
 C                  0.31233895    0.67969088   -0.91453629
 C                  0.72241873    4.18037914    0.45319730
 H                  1.75076677    4.55078807    0.52236893
 H                  0.07792275    5.06381164    0.38944512
 C                  0.58211880    3.23410756   -0.78911453
 H                  1.50268838    3.24039425   -1.38143443
 C                 -0.55238738    3.73802537   -1.65530635
 C                 -0.32378305    4.51257300   -2.74293769
 H                  0.67965911    4.56778197   -3.17733604
 H                 -1.14914259    4.80178335   -3.39684249
 C                 -1.94392543    3.44543996   -1.17242207
 H                 -2.02379189    3.55154121   -0.08595357
 H                 -2.68811303    4.07649544   -1.66337067
 H                 -2.17035062    2.39478690   -1.40175729
 P                 -0.14326798   -3.53609021    0.28918245
 C                  0.32950554   -4.75073778   -1.00542301
 H                  0.19937151   -5.77370143   -0.63719030
 H                 -0.29568960   -4.60070531   -1.89020284
 H                  1.37550069   -4.59501800   -1.28479811
 C                 -1.85709370   -4.00356020    0.75693284
 H                 -1.89995032   -5.05784961    1.04923442
 H                 -2.18764916   -3.38059600    1.59305650
 H                 -2.52516927   -3.83343262   -0.09208385
 C                  0.87117763   -3.99884846    1.74924975
 H                  1.92906402   -3.83931965    1.52199750
 H                  0.59632702   -3.36525654    2.59738761
 H                  0.70919064   -5.04933180    2.01219172
 Au                 0.09442601   -1.29349919   -0.35143275
 C                 -0.25457145    1.42496885    3.56950186
 H                 -0.50296188    0.68889042    4.32931305
 C                  0.24568606    3.71788816    2.96213338
 H                  0.39085729    4.75960325    3.23647049
 Cl                 0.49502979    0.90835353   -2.71604011

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



