%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=9) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  3.24440676   -1.67982322   -0.41173714
 C                  1.92367148   -1.27307396   -0.15315913
 C                  0.97563722   -2.22789875    0.24512304
 C                  2.67428133   -3.96158110    0.09637266
 H                 -0.04372659   -1.93038826    0.47176279
 H                  2.95854043   -5.00467221    0.20139485
 C                  1.80505066    0.18904495   -0.31953310
 C                  0.67190130    0.92593472   -0.28301689
 C                  4.11985366   -0.51781379   -0.81027670
 H                  4.39278861   -0.56118964   -1.86950166
 H                  5.05441826   -0.50185173   -0.24117394
 C                  3.21644335    0.73847522   -0.53886093
 H                  3.24589243    1.41627559   -1.39754972
 C                  3.79002493    1.48421046    0.64383871
 C                  3.36984790    1.25068790    1.92801891
 H                  3.75953058    1.87377887    2.73373013
 H                  2.38070213    0.81823119    2.08860361
 C                  4.93819275    2.39216705    0.34174714
 H                  4.51952601    3.31745629   -0.07914423
 H                  5.51355715    2.65172389    1.23313927
 H                  5.60123134    1.97109108   -0.42186678
 P                 -3.54985714   -0.26825893    0.11705011
 C                 -4.60104866    0.86752855    1.10619514
 H                 -5.62436814    0.48278053    1.16739408
 H                 -4.18651511    0.96148479    2.11387795
 H                 -4.61107392    1.85558457    0.63722771
 C                 -3.75096195   -1.90458534    0.92758813
 H                 -4.81082865   -2.17053636    0.99550264
 H                 -3.22125473   -2.66426371    0.34544523
 H                 -3.31942589   -1.86869870    1.93192618
 C                 -4.43808911   -0.43881830   -1.48189090
 H                 -4.44653911    0.52584710   -1.99723654
 H                 -3.91862100   -1.16757286   -2.11054710
 H                 -5.46787504   -0.77096790   -1.31362727
 Au                -1.30863107    0.38635314   -0.08792286
 C                  1.35658226   -3.56501669    0.36355775
 H                  0.62427729   -4.30405252    0.67686307
 C                  3.62581437   -3.01417377   -0.28948137
 H                  4.65361293   -3.31122452   -0.48555503
 Cl                 0.94389487    2.72303332   -0.45161309

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



