%nprocshared=20
%mem=41GB
#p opt=maxstep=9 freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  1.96778716    2.48660632   -0.77072969
 C                  1.38783007    1.37522311   -0.13228139
 C                  2.19802199    0.47017106    0.56259598
 C                  4.15449776    1.76812277   -0.07161276
 H                  1.75936695   -0.36790923    1.09563586
 H                  5.23025370    1.91612794   -0.03893841
 C                 -0.08224877    1.41316554   -0.32472439
 C                 -0.89081812    0.33159180   -0.33585877
 C                  0.89955730    3.34114013   -1.41478340
 H                  0.83676068    3.13770930   -2.49114730
 H                  1.07537023    4.41491761   -1.30401897
 C                 -0.41326362    2.85911254   -0.73444959
 H                 -1.25801378    2.86656729   -1.43018449
 C                  0.28948650    3.98900243    1.49681128
 H                  1.16859611    4.44900891    1.04216903
 H                 -0.06886207    4.61181076    2.31983801
 H                  0.59314677    3.02733455    1.91835637
 C                 -2.12073931    3.32261981    1.14281554
 H                 -1.99105961    2.32827758    1.57817660
 H                 -2.38858581    4.01134276    1.94810318
 H                 -2.93781510    3.26019526    0.42070673
 P                  0.09446320   -3.93351529    0.19255191
 C                 -0.86195053   -4.81256973    1.49174008
 H                 -0.55373480   -5.86193682    1.54636543
 H                 -0.69087999   -4.33224453    2.45939119
 H                 -1.92891360   -4.75842696    1.25745917
 C                  1.85180812   -4.22877057    0.63957275
 H                  2.04732852   -5.30158743    0.73917266
 H                  2.49892804   -3.81085358   -0.13688999
 H                  2.07443035   -3.72935926    1.58694346
 C                 -0.16970107   -4.93682496   -1.32338764
 H                 -1.22203430   -4.88193602   -1.61659074
 H                  0.44149333   -4.53506287   -2.13652199
 H                  0.10379669   -5.98150150   -1.14277260
 Au                -0.43965427   -1.66607805   -0.05931885
 C                  3.58103683    0.67204961    0.58418348
 H                  4.21478610   -0.02186049    1.12972981
 C                  3.34452687    2.68600801   -0.75092779
 H                  3.78389673    3.54797624   -1.24657431
 C                 -0.81063979    3.71711039    0.48940734
 O                 -1.07696061    5.13954786   -0.21479726
 C                 -1.31809578    6.36224182    0.58033365
 H                 -2.13303683    6.19515462    1.28381411
 H                 -0.38180600    6.58582209    1.08349536
 H                 -1.56259854    7.13882205   -0.14258188
 Cl                -2.63658606    0.62953671   -0.76347504

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



