%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=3) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  1.94803900    2.47801254   -0.78738622
 C                  1.36689209    1.35729822   -0.16741830
 C                  2.17714746    0.43833480    0.50851372
 C                  4.13560302    1.73944757   -0.11283450
 H                  1.73868028   -0.40822544    1.02807436
 H                  5.21214851    1.88228428   -0.08373732
 C                 -0.10689931    1.39956004   -0.36149437
 C                 -0.90218718    0.30926289   -0.39314631
 C                  0.88089940    3.35121978   -1.40650270
 H                  0.81118719    3.17370781   -2.48700530
 H                  1.06243321    4.42123121   -1.27143814
 C                 -0.43018225    2.85970567   -0.73116187
 H                 -1.28156843    2.90013587   -1.41800944
 C                  0.29204577    3.87121305    1.55314052
 H                  1.19162048    4.31861555    1.12652432
 H                 -0.05353847    4.46885263    2.39996521
 H                  0.55938325    2.88285633    1.93514172
 C                 -2.13545463    3.30364236    1.15208512
 H                 -2.04388882    2.28975694    1.55076553
 H                 -2.39142262    3.97150640    1.97885713
 H                 -2.94409075    3.29398442    0.41762741
 P                  0.11147614   -3.93286049    0.24430939
 C                 -0.71362385   -4.72776045    1.68070094
 H                 -0.38057039   -5.76568090    1.78492576
 H                 -0.47155413   -4.17490731    2.59290938
 H                 -1.79739415   -4.70627636    1.53515917
 C                  1.90577390   -4.18881155    0.54659077
 H                  2.12149783   -5.25115150    0.70117693
 H                  2.47363392   -3.82302411   -0.31369977
 H                  2.20995331   -3.62328983    1.43210021
 C                 -0.27630522   -5.03379508   -1.17373012
 H                 -1.35106021   -5.00360485   -1.37415285
 H                  0.25586652   -4.68230182   -2.06226810
 H                  0.02436109   -6.06306887   -0.95211408
 Au                -0.45085517   -1.68405722   -0.08539725
 C                  3.56088858    0.63484541    0.52742204
 H                  4.19437763   -0.07081686    1.05792660
 C                  3.32575822    2.67203613   -0.77139259
 H                  3.76504762    3.54101808   -1.25458936
 C                 -0.80713876    3.67999051    0.52655825
 O                 -1.02698060    5.13942580   -0.11502661
 C                 -1.14132887    6.34351165    0.73471192
 H                 -1.90784497    6.19201445    1.49374558
 H                 -0.15910805    6.50175611    1.17018244
 H                 -1.39994536    7.15641849    0.05866616
 H                 -1.78243870    5.09415726   -0.73685445
 Cl                -2.58670994    0.55739953   -0.83858014

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD




