%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=9) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  2.68880836   -1.84864456    0.36270037
 C                  1.39172220   -1.57818828   -0.12791507
 C                  0.59498571   -2.65100933   -0.57041538
 C                  2.34641901   -4.22307148   -0.03097800
 H                 -0.40198082   -2.44787017   -0.95590677
 H                  2.71884442   -5.24139772    0.01359713
 C                  0.87157559   -0.19452483   -0.15552392
 C                  1.59719021    0.91683128   -0.20613372
 C                  3.56501051   -0.70532976    0.81257832
 H                  3.20265527   -0.30409484    1.76771513
 H                  4.59102642   -1.06224229    0.98018487
 C                  3.58572768    0.38357371   -0.24670660
 H                  3.57453377    0.01849386   -1.27526260
 C                  4.14158228    1.64387740   -0.06617135
 C                  4.42899908    2.23205279    1.27374640
 H                  3.85440089    3.15858977    1.39602165
 H                  5.48859337    2.51999810    1.32170100
 H                  4.20605532    1.56594917    2.10864111
 C                  4.42545246    2.51438650   -1.24410294
 H                  5.49753866    2.75589928   -1.26301205
 H                  3.89726349    3.47134133   -1.14729349
 H                  4.15108167    2.04686152   -2.19073214
 P                 -3.56217123    0.26430088    0.12615686
 C                 -4.14880222    1.06736069    1.66682615
 H                 -5.24314539    1.09883034    1.68433042
 H                 -3.75309208    2.08554962    1.71895194
 H                 -3.78506941    0.50453930    2.53174719
 C                 -4.33768664    1.21287720   -1.23887635
 H                 -5.42380639    1.24746891   -1.10659604
 H                 -4.10022738    0.73528818   -2.19403646
 H                 -3.93836066    2.23079622   -1.24452363
 C                 -4.37693521   -1.37859745    0.09524021
 H                 -4.01262259   -1.98107578    0.93184644
 H                 -4.13146366   -1.88754197   -0.84089975
 H                 -5.46276696   -1.26513736    0.17399304
 Au                -1.25003569    0.11818935   -0.03239114
 C                  1.06746541   -3.96015896   -0.52947727
 H                  0.43938484   -4.77341051   -0.88284233
 C                  3.14670320   -3.16721913    0.40790202
 H                  4.14514402   -3.36711148    0.78664377
 Cl                 1.22012328    2.58844174   -0.16846345

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



