%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=3) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  1.70006383    3.27355819   -0.30796894
 C                  1.32432724    1.92334023   -0.20983759
 C                  2.30536962    0.95484067    0.04654397
 C                  3.99463485    2.70392244    0.11960366
 H                  2.03588919   -0.09466763    0.12549625
 H                  5.03165791    2.99722007    0.25322933
 C                 -0.13364940    1.78477581   -0.36641591
 C                 -0.88510512    0.66651382   -0.29678734
 C                  0.53522009    4.17676704   -0.61815908
 H                  0.58377673    4.63552792   -1.61106806
 H                  0.45272189    5.00232088    0.10084979
 C                 -0.72009056    3.18365786   -0.61476460
 H                 -1.23860239    3.24225906   -1.57328195
 C                 -1.56018226    3.71630012    0.45680804
 C                 -2.66157180    4.64717446    0.16672985
 H                 -2.92405736    4.69750963   -0.88943863
 H                 -3.53514527    4.38833593    0.77676984
 H                 -2.35525026    5.64423816    0.52187721
 C                 -1.24434972    3.39544234    1.85963658
 H                 -1.61917836    4.14235864    2.56222928
 H                 -1.76786928    2.44608100    2.06344071
 H                 -0.18008757    3.18902744    2.00712096
 P                  0.24980606   -3.57125508    0.13030291
 C                 -0.83298889   -4.55359579    1.24184135
 H                 -0.48478509   -5.59027144    1.29759550
 H                 -0.82278882   -4.11215642    2.24251483
 H                 -1.85785236   -4.53426336    0.86068993
 C                  1.94232936   -3.80798214    0.80220605
 H                  2.18016402   -4.87475264    0.86688494
 H                  2.66563499   -3.31334289    0.14778426
 H                  2.00578564   -3.35975953    1.79790600
 C                  0.25188260   -4.49810273   -1.45547069
 H                 -0.75250047   -4.48274105   -1.88799501
 H                  0.94271101   -4.01894731   -2.15494049
 H                  0.56219289   -5.53482349   -1.29030638
 Au                -0.36604405   -1.32068345   -0.08398589
 C                  3.63222883    1.35236691    0.20726065
 H                  4.39280774    0.60398777    0.41056870
 C                  3.02361309    3.67445249   -0.13628128
 H                  3.29476022    4.72412560   -0.20613172
 Cl                -2.67470510    0.97323306   -0.41830131

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



