%nprocshared=20
%mem=41GB
#p opt=(maxstep=17) freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.46481305   -2.16038971   -0.55385931
 C                 -0.63532996   -1.48718806    0.00994973
 C                 -1.66639991   -2.22798044    0.60486205
 C                 -0.50380925   -4.28581106    0.03789527
 H                 -2.50671083   -1.72366793    1.07325548
 H                 -0.45766460   -5.37144224    0.05617892
 C                  1.45532126   -1.18299086   -1.13744811
 H                  1.38958988   -1.17770338   -2.23378587
 H                  2.49069276   -1.43277227   -0.88148579
 C                  1.00896952    0.19732830   -0.55399786
 H                  1.05630461    0.96717191   -1.33125400
 C                  1.93636872    0.62550552    0.58053967
 C                  1.65578199    0.42877121    1.87258192
 H                  2.35957320    0.71074133    2.65212661
 H                  0.71439996   -0.00636290    2.19539341
 C                  3.22967015    1.25576413    0.12494488
 H                  3.02871158    2.19439593   -0.40970267
 H                  3.89711206    1.47429090    0.96444983
 H                  3.76597948    0.60482523   -0.57877491
 C                 -1.59669750   -3.62246732    0.61084449
 H                 -2.39294641   -4.19710308    1.07720647
 C                  0.53456058   -3.55160220   -0.54450453
 H                  1.39030225   -4.06093350   -0.98153959
 C                 -1.55761493    1.08871639    0.09906057
 H                 -2.51020499    0.67257849    0.35263782
 Cl                -0.95459700    2.88468283   -0.14378488
 C                 -0.59247137   -0.02902451   -0.42344553
 H                 -1.21321818    0.09029398   -1.28677427

C H Cl 0
6-31G*
****








