%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=2) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  2.24770027   -1.37995264   -0.49914851
 C                  1.81606360   -1.05385277    0.81585565
 C                  2.09208157   -1.90954519    1.90637985
 C                  3.24761101   -3.40583083    0.41859281
 H                  1.74097560   -1.63370474    2.89561820
 H                  3.81193927   -4.31878921    0.25274391
 C                  1.11400531    0.14963661    1.07041393
 C                  0.47592770    1.18951635    1.32468315
 C                  1.91161167   -0.50569582   -1.69466195
 H                  0.83585849   -0.60717179   -1.89531349
 H                  2.41947606   -0.92172287   -2.57280616
 C                  2.22753365    0.97342788   -1.54461382
 H                  1.36533396    1.63762129   -1.53580642
 C                  3.44773091    1.51513957   -1.41459077
 C                  4.72783747    0.71730993   -1.40103928
 H                  5.42768293    1.10356236   -2.15400215
 H                  5.22997268    0.81580654   -0.42874088
 H                  4.57604491   -0.34772118   -1.59068833
 C                  3.62405928    3.00521017   -1.25260441
 H                  4.13508101    3.23431551   -0.30723346
 H                  4.25345725    3.41552962   -2.05415434
 H                  2.66675198    3.53641843   -1.26024734
 P                 -3.17761323   -0.47201605   -0.71240574
 C                 -4.63959757    0.47290619   -0.14198322
 H                 -5.53666752    0.11818327   -0.65951422
 H                 -4.76223340    0.34069127    0.93629094
 H                 -4.49186222    1.53520417   -0.35448633
 C                 -3.55998926   -2.23558361   -0.39322320
 H                 -4.49472269   -2.51106352   -0.89193610
 H                 -2.74597843   -2.85853965   -0.77393306
 H                 -3.65744006   -2.39804849    0.68358801
 C                 -3.15225678   -0.28932209   -2.53502656
 H                 -3.00606034    0.76293615   -2.79357434
 H                 -2.32736303   -0.87451297   -2.95022777
 H                 -4.09945415   -0.64109446   -2.95724230
 Au                -1.21293308    0.21968421    0.31140817
 C                  2.81237463   -3.07987786    1.70744564
 H                  3.03376889   -3.73232286    2.54571097
 C                  2.96402213   -2.56688830   -0.66304996
 H                  3.31057164   -2.83945303   -1.65594755
 Cl                 0.45061681    2.78408699    1.84624541

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD



