%nprocshared=20
%mem=41GB
#p opt=(maxstep=17) freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  0.48744203   -2.05966801   -0.63856606
 C                 -0.61510781   -1.43548182   -0.02523808
 C                 -1.59024981   -2.22147337    0.60493223
 C                 -0.36949175   -4.22654652   -0.02527936
 H                 -2.43045932   -1.75483440    1.11103699
 H                 -0.27877599   -5.30949217   -0.01766120
 C                 -0.48834644    0.03269700   -0.15627424
 C                  1.41298316   -1.03899642   -1.25386602
 H                  1.30242234   -1.02933342   -2.34656359
 H                  2.46718775   -1.24803814   -1.04207404
 C                  0.93535150    0.31821087   -0.64167206
 H                  0.91976954    1.09433119   -1.41395526
 C                  1.89018706    0.77649717    0.45780197
 C                  2.89058874    1.63830568    0.24974179
 H                  3.52575741    1.97333921    1.06633988
 H                  3.11656881    2.02708167   -0.73896207
 C                  1.58759734    0.20939629    1.82318000
 H                  1.70850331   -0.88267233    1.81771283
 H                  2.24458812    0.62427028    2.59405218
 H                  0.54765628    0.40643975    2.11689272
 C                 -1.46402731   -3.61197318    0.59680745
 H                 -2.21669923   -4.22155671    1.09037100
 C                  0.61371475   -3.44691608   -0.64329672
 H                  1.47081171   -3.91814288   -1.11873540
 C                 -1.46141564    0.93739842    0.07957177
 H                 -2.38526038    0.48117927    0.36814581
 Cl                -0.94192643    2.75796367   -0.17296160

C H Cl 0
6-31G*
****








