%nprocshared=20
%mem=41GB
#p opt=maxstep=9 freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.74520100    3.74042100    0.79498400
 C                  0.71486400    2.33264100    0.71973900
 C                  1.37100000    1.55907000    1.69411700
 C                  2.06346200    3.60662700    2.80119300
 H                  1.34774500    0.47619200    1.64895600
 H                  2.58339400    4.09372500    3.62202300
 C                 -0.03646000    1.92467200   -0.46866900
 C                 -0.06750700    0.64569200   -0.98016000
 C                  0.02035400    4.36340600   -0.36762500
 H                  0.72791700    4.84499000   -1.05098300
 H                 -0.69188500    5.13617900   -0.05428800
 C                 -0.68347900    3.16517000   -1.07338600
 H                 -0.50182200    3.17759000   -2.15191600
 C                 -2.19327000    3.16512700   -0.84011300
 C                 -3.04040000    3.35414500   -1.85448400
 H                 -2.69323300    3.47533900   -2.87732600
 H                 -4.11531700    3.39258100   -1.69438400
 C                 -2.65726000    2.96867900    0.58228300
 H                 -2.18313700    3.68445500    1.26579300
 H                 -3.74178200    3.08380500    0.66440500
 H                 -2.39272300    1.96668500    0.94628000
 P                 -0.66908600   -3.04722000    1.45190900
 C                 -0.28660900   -4.56133400    0.48767300
 H                 -0.38910500   -5.44985000    1.11628900
 H                 -0.97303500   -4.63301200   -0.36070800
 H                  0.73580400   -4.48975400    0.10460700
 C                 -2.37887700   -3.28697000    2.07067400
 H                 -2.44865700   -4.22472500    2.63107400
 H                 -2.64960100   -2.45143300    2.72217300
 H                 -3.07190000   -3.31287700    1.22528700
 C                  0.39324400   -3.16091600    2.94375800
 H                  1.44452100   -3.11769000    2.64508400
 H                  0.18063700   -2.31949900    3.60920500
 H                  0.20036900   -4.10093400    3.46974800
 Au                -0.33967200   -1.10567600    0.22353600
 C                  2.04352400    2.20247000    2.72896200
 H                  2.54818900    1.61720100    3.48932500
 C                  1.41704200    4.37854600    1.83585500
 H                  1.43731700    5.46343300    1.89220900
 Cl                -0.91481300    0.44850700   -2.58527600
 H                  1.10145000    0.23457200   -1.13689900

C H P Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

