%nprocshared=20
%mem=41GB
#p opt=(calcall,maxstep=2) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq very shallow calcall

1 1
 C                  0.74520100    3.73652100    0.79498400
 C                  0.71096400    2.33264100    0.72363900
 C                  1.37100000    1.56297000    1.69411700
 C                  2.06346200    3.60662700    2.80509300
 H                  1.35164500    0.47619200    1.64895600
 H                  2.58729400    4.09372500    3.62202300
 C                 -0.03646000    1.91687200   -0.47646900
 C                 -0.11430700    0.64569200   -0.94896000
 C                  0.02035400    4.36340600   -0.36762500
 H                  0.73181700    4.85279000   -1.04708300
 H                 -0.69188500    5.13227900   -0.05428800
 C                 -0.67957900    3.16907000   -1.08118600
 H                 -0.50572200    3.19709000   -2.15971600
 C                 -2.18937000    3.16512700   -0.84011300
 C                 -3.04040000    3.35414500   -1.85448400
 H                 -2.69323300    3.47533900   -2.87732600
 H                 -4.11531700    3.38868100   -1.69438400
 C                 -2.65726000    2.96867900    0.58228300
 H                 -2.18313700    3.68445500    1.26579300
 H                 -3.74178200    3.08380500    0.66440500
 H                 -2.38882300    1.96668500    0.94238000
 P                 -0.66908600   -3.04722000    1.45190900
 C                 -0.28660900   -4.56133400    0.48767300
 H                 -0.38910500   -5.45375000    1.11628900
 H                 -0.97303500   -4.63301200   -0.36070800
 H                  0.73580400   -4.48975400    0.10850700
 C                 -2.37887700   -3.28697000    2.07067400
 H                 -2.45255700   -4.22472500    2.63107400
 H                 -2.64960100   -2.45143300    2.72217300
 H                 -3.07190000   -3.31287700    1.22528700
 C                  0.39324400   -3.16091600    2.94375800
 H                  1.44452100   -3.11769000    2.64508400
 H                  0.18063700   -2.31949900    3.60920500
 H                  0.20426900   -4.10093400    3.47364800
 Au                -0.33967200   -1.10567600    0.22353600
 C                  2.04352400    2.20637000    2.72896200
 H                  2.55208900    1.61720100    3.48932500
 C                  1.41704200    4.37854600    1.83585500
 H                  1.43731700    5.46343300    1.89220900
 Cl                -0.91481300    0.44850700   -2.58527600
 H                  1.46415000    0.14487200   -1.19539900
 O                  2.36369400   -0.15738600   -1.46771300
 H                  2.29095871   -1.29105683   -1.56429475
 C                  2.77337600    0.47632900   -2.72670700
 H                  2.08476300    0.19375500   -3.52245800
 H                  2.75183100    1.54954900   -2.55027300
 H                  3.78855500    0.13920400   -2.93112300
 O                  2.02896500   -2.71332000   -1.63513100
 H                  2.84152200   -3.24026100   -1.71419100
 C                  1.10265900   -3.10716900   -2.67549700
 H                  0.22218100   -2.47307700   -2.55747100
 H                  1.53858100   -2.95161600   -3.66812100
 H                  0.81888200   -4.15463400   -2.54657000

C H P O Cl 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD

