%nprocshared=20
%mem=41GB
#p opt=maxstep=17 freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  2.76591298   -2.04340609   -0.50231186
 C                  1.44648112   -1.88338925   -0.01484164
 C                  0.77774788   -3.02665786    0.45955731
 C                  2.68305113   -4.42855293   -0.04122399
 H                 -0.23560357   -2.92022976    0.84101931
 H                  3.16368914   -5.40339227   -0.05355049
 C                  0.81697617   -0.53989463   -0.04247032
 C                  1.63181348    0.55733854   -0.08313490
 C                  3.48011473   -0.80975225   -1.01509965
 H                  4.55480397   -0.99613468   -1.05917410
 H                  3.14700468   -0.61660275   -2.05018401
 C                  3.11432011    0.37933759   -0.15000625
 C                  4.02066447    1.14203981    0.50517139
 C                  3.64942162    2.21642027    1.50628242
 H                  3.76575204    3.22459775    1.08316808
 H                  4.32815496    2.16330466    2.36809788
 H                  2.63071546    2.12132722    1.88492313
 C                  5.52006265    1.00354475    0.35622871
 H                  5.97179767    0.62141521    1.28313619
 H                  5.96828011    1.99233700    0.18290376
 H                  5.83308741    0.35444810   -0.46345224
 P                 -3.61342534   -0.22378474    0.00523238
 C                 -4.32420029    0.63022692    1.47210284
 H                 -5.41615012    0.67851194    1.40190961
 H                 -3.91977822    1.64498670    1.53202049
 H                 -4.04188397    0.08938156    2.38015273
 C                 -4.32628508    0.69478425   -1.42090804
 H                 -5.41926560    0.72156740   -1.35593230
 H                 -4.02941440    0.20546153   -2.35316731
 H                 -3.93779397    1.71743442   -1.42547092
 C                 -4.49244247   -1.83956927   -0.03193727
 H                 -4.20751342   -2.42844328    0.84487193
 H                 -4.20108860   -2.39072964   -0.93085600
 H                 -5.57749003   -1.69068622   -0.03263530
 Au                -1.25784640   -0.38692614   -0.00834334
 C                  1.38560588   -4.28383663    0.45415504
 H                  0.84471333   -5.14741433    0.83349830
 C                  3.36447984   -3.30318074   -0.51764736
 H                  4.37838498   -3.40574035   -0.90008314
 C                  1.05481032    1.98341873   -0.15358096
 C                  1.50853842    2.87207199   -1.12872076
 C                  0.07853854    2.38663633    0.75738397
 C                  0.98654313    4.16384980   -1.19238188
 H                  2.27877567    2.55412566   -1.84627669
 C                 -0.44442951    3.67845559    0.69321787
 H                 -0.27931205    1.68630971    1.52589851
 C                  0.00948327    4.56710311   -0.28136193
 H                  1.34457953    4.86455431   -1.96057433
 H                 -1.21446413    3.99596360    1.41134710
 H                 -0.40198535    5.58565457   -0.33178837

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD




