%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=17) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  2.71881797   -2.21983745    0.26596493
 C                  1.34619876   -2.02331768   -0.01801093
 C                  0.57697495   -3.15359367   -0.35523272
 C                  2.51004649   -4.59542935   -0.15506479
 H                 -0.47800540   -3.01969633   -0.57867226
 H                  2.95851250   -5.58334830   -0.20536798
 C                  0.76998463   -0.66413912   -0.00237998
 C                  1.60982175    0.40668293   -0.09077769
 C                  3.53371055   -1.03217291    0.67988120
 H                  3.30000857   -0.73357678    1.70735377
 H                  4.60418470   -1.24134242    0.61058198
 C                  3.11771190    0.17831237   -0.28418583
 H                  3.34735231   -0.14668982   -1.30622894
 C                  4.01890268    1.24218781    0.12467541
 C                  3.83470325    1.96724754    1.39448998
 H                  3.54870333    3.00062786    1.13637835
 H                  4.78152315    2.03895324    1.94161356
 H                  3.04230214    1.55508993    2.02016923
 C                  5.15639617    1.60475145   -0.74133543
 H                  5.99174616    2.04350149   -0.19011247
 H                  4.78277772    2.37337874   -1.44062362
 H                  5.48637679    0.76320211   -1.35996146
 P                 -3.62151676   -0.02241997    0.01584256
 C                 -4.52493336   -0.88237287    1.36594738
 H                 -5.59469356   -0.65215468    1.31828398
 H                 -4.12823901   -0.56156871    2.33342637
 H                 -4.38134857   -1.96269030    1.27004415
 C                 -4.10744339    1.74178850    0.20925126
 H                 -5.19797065    1.84129829    0.20353228
 H                 -3.68293010    2.32780044   -0.61089589
 H                 -3.71117932    2.12606195    1.15325759
 C                 -4.47830249   -0.56275280   -1.51696081
 H                 -4.31195909   -1.63372397   -1.66425670
 H                 -4.06601119   -0.02365291   -2.37470155
 H                 -5.55350792   -0.36767003   -1.44733470
 Au                -1.30124587   -0.37565900    0.00784410
 C                  1.14817116   -4.42224651   -0.42434024
 H                  0.53386548   -5.27677545   -0.69377017
 C                  3.29347757   -3.49032035    0.17978393
 H                  4.35203539   -3.61587795    0.39283789
 C                  1.14237860    1.81726028   -0.12201355
 C                  1.51779177    2.66215037   -1.18328838
 C                  0.33884235    2.34919211    0.90134577
 C                  1.08301128    3.98790304   -1.23071515
 H                  2.12756396    2.27114096   -1.99395625
 C                 -0.09521252    3.67596436    0.85443876
 H                  0.06661809    1.71695516    1.74023361
 C                  0.27323483    4.49997695   -0.21201729
 H                  1.37059084    4.61743557   -2.06730630
 H                 -0.71173628    4.06701416    1.65833118
 H                 -0.06111454    5.53210043   -0.24742241

C H P 0
6-31G*
****
Au 0
SDD
****

Au 0
SDD










