%nproc=20
%Mem=40000MB
%Chk=AC01-Br-TS1-2-6endo_less
#p SCRF=(PCM,Solvent=Dichloromethane) B3LYP/genecp opt EmpiricalDispersion=GD3 freq=noraman nosymm
# scf(maxcyc=100) gfinput gfprint

opt freq

1 1
 C                 -2.62680300   -0.22202600    6.80787400
 C                 -1.86951100    0.74505300    6.45386100
 C                 -1.97695400    2.20272100    6.41352400
 C                 -3.24253800    2.81518500    6.26354400
 C                 -0.82232100    2.99838900    6.52607300
 H                  0.14243200    2.51392300    6.64887200
 C                 -2.15467500    4.99691100    6.33236700
 H                 -2.23386000    6.07942100    6.29588900
 C                 -4.50901900    1.99722900    6.12147700
 H                 -4.50822000    1.52627200    5.12901300
 H                 -5.37340300    2.67370200    6.12508600
 C                 -4.74993800    0.89637600    7.13467400
 H                 -5.31739700    0.05595300    6.73979000
 C                 -4.52404800    0.90117900    8.47897500
 C                 -4.97446000   -0.26003700    9.32387300
 H                 -4.12820700   -0.68304700    9.88124800
 H                 -5.43793000   -1.05534900    8.73489000
 H                 -5.70089300    0.08487800   10.07164800
 C                 -3.84139100    2.00701700    9.23936600
 H                 -4.34961000    2.16805300   10.19671500
 H                 -3.81046000    2.95113400    8.69575300
 H                 -2.80772100    1.71921400    9.47470100
 Au                -0.09740200   -0.25431500    5.70347700
 P                  1.89001600   -1.07364500    4.83266100
 C                  3.26628300    0.12617200    4.99563400
 H                  3.00652300    1.05017000    4.47164600
 H                  4.18218100   -0.29290500    4.56600100
 H                  3.42907300    0.35218400    6.05305600
 C                  1.79549500   -1.46694700    3.04509200
 H                  1.02805700   -2.22791400    2.87873700
 H                  2.76267000   -1.83944300    2.69232900
 H                  1.52647800   -0.56518100    2.48837400
 C                  2.48143300   -2.60874100    5.64135900
 H                  2.62379700   -2.42637100    6.70985500
 H                  3.43018400   -2.92356100    5.19466900
 H                  1.73674000   -3.39941700    5.51293600
 Br                -3.02223900   -1.99046000    6.99060100
 C                 -0.90864400    4.38718400    6.49609900
 H                 -0.00942500    4.98821300    6.59409600
 C                 -3.30338200    4.21227900    6.21792400
 H                 -4.27174300    4.69186300    6.09653800

C H P 0
6-31G*
****
Br 0
LANL2DZ
D 1 1.0
0.428 1.0
****
Au 0
SDD 
****

Br 0
LANL2DZ
Au 0
SDD




