%nprocshared=12
%mem=22GB
#p opt=(maxstep=17) freq=noraman b3lyp genecp scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                 -0.29680098   -1.92253690   -0.70697429
 C                 -1.17723930   -1.07196407    0.01723380
 C                 -2.25484094   -1.60259260    0.76229323
 C                 -1.59557420   -3.82032655    0.10232079
 H                 -2.91194434   -0.92375286    1.29658277
 H                 -1.74740600   -4.89528739    0.13202384
 C                 -0.98478836    0.32999068    0.01411205
 C                 -0.84889632    1.56944937   -0.00589374
 C                  0.83757910   -1.36787462   -1.55033727
 H                  0.39670926   -0.86251317   -2.42086579
 H                  1.40741411   -2.21414438   -1.95199586
 C                  1.76162344   -0.38376532   -0.85058774
 H                  1.74003357    0.63365672   -1.23626703
 C                  2.57461333   -0.65370254    0.18166730
 C                  2.70477418   -2.01364453    0.82109222
 H                  3.75649617   -2.32923042    0.83790599
 H                  2.37300088   -1.97811004    1.86792342
 H                  2.12446011   -2.78768718    0.31402292
 C                  3.43245895    0.42402734    0.79841019
 H                  3.19973102    0.54143123    1.86581131
 H                  4.49716238    0.15948159    0.73936472
 H                  3.29066426    1.39344235    0.30974124
 C                 -2.45766627   -2.97529540    0.80957082
 H                 -3.27831817   -3.38528888    1.38904101
 C                 -0.53637926   -3.29618939   -0.64454501
 H                  0.12061429   -3.97035957   -1.18691655
 Br                -0.62633708    3.46642598   -0.01275846

C H 0
6-31G*
****
Br 0
LanL2DZ
D 1 1.0
0.428 1.0
****

Br 0
LanL2DZ







