%nprocshared=20
%mem=41GB
#p opt freq=noraman scrf=(solvent=dichloromethane,pcm) nosymm b3lyp gen empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  1.05961838    2.19364962   -1.83869744
 H                  1.94776204    2.18913284   -1.19729004
 H                  0.09522806    0.29185001   -1.53531478
 O                  0.05781156   -1.47440263   -1.33545012
 C                 -1.14287025   -2.11654897   -1.82993851
 H                 -1.14075165   -3.18014704   -1.57542683
 O                  0.06199655    1.26565731   -1.36339385
 H                 -1.22749056   -1.98716937   -2.91274961
 H                 -1.97899596   -1.62283852   -1.33333993
 H                  0.63601164    3.20105723   -1.87972841
 H                  1.33507707    1.87505229   -2.84510353
 H                  0.11835626   -1.45087048    0.44497381
 O                  0.07707350   -1.17250553    1.39275617
 C                  1.24626124   -1.65671442    2.08344625
 H                  2.16825256   -1.27850041    1.62691082
 H                  1.25387648   -2.75060203    2.07837452
 H                  1.17817343   -1.30148575    3.11293531
 H                 -0.05993875    0.27583039    1.33014515
 O                 -0.14100325    1.31012815    1.11583527
 C                 -1.30040518    1.77333842    1.87299179
 H                 -0.08981148    1.37130344    0.05076311
 H                 -2.17184387    1.15148560    1.65365436
 H                 -1.48055387    2.80913273    1.58704556
 H                 -1.04001785    1.71228763    2.92905284
 H                  0.83401428   -1.89888482   -1.73969462

C H O 0
6-31G*
****





