%nprocshared=20
%mem=41GB
#p opt freq=noraman scrf=(solvent=dichloromethane,pcm) nosymm b3lyp gen empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.21059815    0.89747713   -2.76819331
 H                 -0.87046677    0.76740588   -2.64734994
 H                  0.74711423   -0.39548396   -1.33377801
 O                  0.23274251   -1.88000331   -0.50154110
 C                 -0.95908237   -2.49911526   -1.04446038
 H                 -1.27349265   -3.33877871   -0.41825514
 O                  0.92089078    0.55178663   -1.56058618
 H                 -0.78120672   -2.83765557   -2.06921902
 H                 -1.73155228   -1.72922415   -1.03953198
 H                  0.56895976    0.27947825   -3.59623356
 H                  0.43069515    1.94552720   -2.97647999
 H                 -0.07559910   -1.10169098    1.07112675
 O                 -0.24347996   -0.44002732    1.78631898
 C                  0.59876075   -0.73698300    2.91811354
 H                  1.65997619   -0.72370701    2.64391660
 H                  0.33620935   -1.71606891    3.32936937
 H                  0.40750122    0.03210504    3.66817651
 H                 -0.00148458    0.84408463    1.14377391
 O                  0.22259056    1.68584062    0.54085665
 C                 -0.91765545    2.58538572    0.69158902
 H                  0.50837724    1.27526196   -0.40280264
 H                 -1.85035095    2.05708095    0.47901339
 H                 -0.77201183    3.41140050   -0.00380740
 H                 -0.90673370    2.94901689    1.71845161
 H                  0.94638783   -2.54011248   -0.46905041

C H O 0
6-31G*
****





