%nprocshared=20
%mem=41GB
#p opt freq=noraman scrf=(solvent=dichloromethane,pcm) nosymm b3lyp gen empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.19488291    0.68111909   -2.84825693
 H                 -0.88226840    0.54016469   -2.70648276
 H                  0.74889454   -0.62242928   -1.28964893
 O                  0.29223620   -1.92432772   -0.38761281
 C                 -0.89263093   -2.60299675   -0.87135420
 H                 -1.18479834   -3.40085576   -0.18281898
 O                  0.92327584    0.43683219   -1.62674141
 H                 -0.71814465   -3.01139549   -1.87092639
 H                 -1.67967931   -1.84917472   -0.91346815
 H                  0.55707964    0.01159998   -3.63346647
 H                  0.39277207    1.71525596   -3.13397670
 H                  0.09594920   -1.49627308    0.69843783
 O                 -0.18955678   -0.33175670    1.79555358
 C                  0.66908728   -0.53048695    2.93649516
 H                  1.72716434   -0.51745655    2.65041550
 H                  0.42937996   -1.48196198    3.42013705
 H                  0.47029852    0.28715102    3.63120536
 H                  0.03937365    0.97752676    1.00071559
 O                  0.22354579    1.70675125    0.39500216
 C                 -0.93228418    2.59360928    0.49299447
 H                  0.60054263    1.05676902   -0.76620927
 H                 -1.85665011    2.03416803    0.32932303
 H                 -0.80924758    3.36973559   -0.26170985
 H                 -0.91847895    3.03067085    1.49078217
 H                 -1.24252611   -0.59095523    1.86880781

C H O 0
6-31G*
****







