%nprocshared=20
%mem=41GB
#p opt freq=noraman scrf=(solvent=dichloromethane,pcm) nosymm b3lyp gen empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                 -0.19719222   -3.73975702    0.45364497
 H                 -0.16039830   -3.16431418    1.39289302
 H                 -0.62805457   -2.24898188   -0.69462344
 O                  0.23565353   -0.60356464   -0.71736051
 C                  1.65001043   -0.79805022   -0.84244492
 H                  2.17177089    0.17006111   -0.79987453
 O                 -1.00358016   -3.13369720   -0.52691313
 H                  1.80790565   -1.25023924   -1.82361061
 H                  2.04750241   -1.46752648   -0.06754001
 H                  0.83921218   -3.89375481    0.11686734
 H                 -0.62435550   -4.72258604    0.68198347
 H                 -0.02781244   -0.18580819    0.12798221
 O                 -0.50228902    1.25189913    1.28948150
 C                  0.35862746    1.42680690    2.46378430
 H                  1.37748810    1.51980938    2.09234500
 H                  0.26544831    0.54698266    3.10082780
 H                  0.07549467    2.33439288    3.00135723
 H                 -0.42933534    1.99662881    0.51022390
 O                 -0.10501276    2.83823066   -0.50754286
 C                 -0.51161266    2.40209773   -1.86413380
 H                 -0.36563181    3.75011318   -0.29713320
 H                 -1.58673194    2.50006482   -2.00042189
 H                 -0.17316844    1.36867273   -1.91927459
 H                  0.02986450    3.03972349   -2.56305543
 H                 -1.41636923    1.13723384    1.57463053

C H O 0
6-31G*
****







