%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.44455030   -3.74547721    0.30653242
 H                  0.53441302   -3.35327763    1.32473557
 H                 -0.23014606   -1.72906222   -0.47802706
 O                  0.18481771   -0.60268549   -0.63331295
 C                 -0.13983339   -0.00914138   -1.96570221
 H                 -1.23128538    0.05617484   -2.02062618
 O                 -0.55811569   -2.88521546   -0.39390848
 H                  0.23775174   -0.69680997   -2.69332943
 H                  0.30668896    0.96239810   -2.00606138
 H                  1.36118818   -3.62382311   -0.23186827
 H                  0.06728233   -4.74674998    0.31119569
 H                 -0.11536052   -0.02766582    0.07439139
 O                 -0.47916996    0.71398277    0.95127817
 C                  0.17947819    0.45642097    2.26879526
 H                  1.25113722    0.62323560    2.11928522
 H                 -0.01883236   -0.56946364    2.49930274
 H                 -0.22377009    1.15141300    2.97539054
 H                 -0.36737504    1.63129908    0.69121530
 O                 -0.20781228    2.78484337    0.38266116
 C                  0.51710504    2.96633542   -0.91254627
 H                 -1.05938933    3.26199931    0.36960570
 H                 -0.10388873    2.50122976   -1.68499493
 H                  1.44529053    2.44525528   -0.80370158
 H                  0.62073638    4.01761914   -1.08273170
 H                 -1.61249544   -3.25483520   -0.55541105

C H O 0
6-31G*
****














