%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  1.27112080   -3.17124993   -0.92540265
 H                  2.01171742   -2.36494396   -0.92996265
 H                 -0.28646807   -1.82039435    0.01575854
 O                 -0.93415031   -0.82886786   -0.23407362
 C                 -2.37768334   -0.93088234    0.13843072
 H                 -2.41146462   -1.05293355    1.22586469
 O                  0.30671389   -2.85704218    0.17332372
 H                 -2.74706477   -1.80565095   -0.35476017
 H                 -2.85578734   -0.02207026   -0.16219727
 H                  0.69704165   -3.16762027   -1.82835334
 H                  1.72730887   -4.11217047   -0.69855252
 H                 -0.53666698   -0.05176581    0.16557551
 O                 -0.03090396    0.93184031    0.64312458
 C                  1.23406887    0.65507159    1.39095451
 H                  1.94081554    0.24025945    0.66495624
 H                  0.98095927   -0.07080863    2.13522156
 H                  1.58831513    1.58424969    1.78597049
 H                  0.11350438    1.60222546   -0.02868641
 O                  0.32069483    2.43964701   -0.86959522
 C                  0.04833512    3.83569609   -0.40821259
 H                  1.22927867    2.36420590   -1.21861636
 H                  0.73294834    4.02786107    0.42426012
 H                 -0.96855092    3.84053722   -0.07531723
 H                  0.24518821    4.49364981   -1.22872814
 H                  0.18504093   -3.50106105    1.23071135

C H O 0
6-31G*
****










