%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.75532878   -2.29103921   -0.33081870
 H                  1.19413376   -1.60238242   -1.07129946
 H                 -0.65091345   -1.09915345    0.32223774
 O                 -1.40200882    0.21766310   -0.58625489
 C                 -2.39678104    0.86072966    0.20962728
 H                 -2.06567294    1.00468598    1.24787227
 O                  0.10659620   -1.60881094    0.72921259
 H                 -3.28220919    0.21892721    0.21299112
 H                 -2.67616807    1.83813777   -0.20779361
 H                  0.08036764   -2.97855287   -0.86510797
 H                  1.56969277   -2.88375224    0.09962664
 H                 -0.02081296    0.90651801   -0.18390142
 O                  0.87156899    1.20609013    0.39407104
 C                  2.12760363    1.56040233   -0.20587532
 H                  0.78045797    0.33221207    0.80477154
 H                  2.17610082    2.63147057   -0.44099253
 H                  2.19417173    0.99369915   -1.13700363
 H                  2.96642450    1.29725170    0.45062255
 H                 -1.79173183    0.04084354   -1.56585280

C H O 0
6-31G*
****











