%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.70597824   -2.47055827   -0.60599200
 H                  1.17145661   -1.79072188   -1.32695374
 H                 -0.11213135   -0.73383908    0.59865790
 O                 -0.90300963    0.17732232    0.50206786
 C                 -2.18185983    0.06874148   -0.26324674
 H                 -2.81556928    0.89740227    0.06884352
 H                  1.46879465   -1.48266621    1.02460474
 O                  0.58584199   -1.71259592    0.67738914
 H                 -2.60994403   -0.87237475    0.01233293
 H                 -1.94650552    0.15667202   -1.30333163
 H                 -0.29483071   -2.71066600   -0.89861760
 H                  1.32683566   -3.32270478   -0.42355732
 H                 -0.45314903    0.99910487    0.29254723
 O                  0.10098232    2.02955724    0.00542926
 C                  1.58154842    1.89245587   -0.15310791
 H                 -0.29495990    2.42591624   -0.79404621
 H                  1.74293368    1.19042271   -0.97756999
 H                  1.93811372    1.48576432    0.77012724
 H                  1.97443703    2.85958671   -0.38804725

C H O 0
6-31G*
****






