%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.77099013   -2.61762939   -0.45012896
 H                  1.60715536   -2.02507935   -0.83528558
 H                 -0.36728394   -0.74707015    0.13469453
 O                 -0.89854035    0.21680230   -0.36904123
 C                 -2.24527540    0.53711433    0.19368337
 H                 -2.09119612    0.78835513    1.24804951
 H                  0.68459672   -1.59204986    1.32677513
 O                  0.08708259   -1.77183552    0.57598507
 H                 -2.82461726   -0.35714284    0.09587169
 H                 -2.63347944    1.37367603   -0.34886815
 H                  0.04399073   -2.79454579   -1.21502926
 H                  1.11933131   -3.50360208    0.03834911
 H                 -0.32377885    0.98455109   -0.32648519
 O                  0.40096734    1.94648983   -0.29915046
 C                  1.72987188    1.68064974    0.33278985
 H                  0.51454009    2.32146087   -1.19331469
 H                  2.21901395    0.91654873   -0.28000959
 H                  1.51815227    1.30649875    1.31262954
 H                  2.28397887    2.59593851    0.32221033

C H O 0
6-31G*
****




