%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                  0.20630840   -1.89273293    0.60520233
 H                 -0.36583987   -1.46530605    1.43501320
 H                 -0.04448957   -0.00454457   -0.62301725
 O                  0.27728230    1.16226222   -0.61540310
 H                  1.24539341    1.25592540   -0.69789977
 C                 -0.22576659    1.92812704    0.56499808
 H                  0.23594393    1.47722769    1.44934162
 H                 -1.19443319   -1.37782879   -0.80528060
 O                 -0.25173724   -1.19125054   -0.63339504
 H                 -1.28647835    1.78785234    0.57565481
 H                  0.08163461    2.94617443    0.44674407
 H                  1.24738122   -1.66537684    0.70203508
 H                 -0.00672345   -2.93458172    0.48659151

C H O 0
6-31G*
****




