%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

1 1
 C                 -0.27943965   -2.18652382   -0.27561391
 H                  0.45573456   -2.29297228   -1.07986578
 H                  0.25826094   -0.00371751    0.01233212
 O                  0.20713208    1.05422142   -0.57348718
 H                  1.06996402    1.27050911   -0.97543033
 C                 -0.28374951    2.19263358    0.26078321
 H                  0.44386854    2.32433896    1.06810965
 H                  1.04827804   -1.28233168    1.00355287
 O                  0.19364903   -1.06050433    0.58709926
 H                 -1.23202210    1.88457291    0.64908427
 H                 -0.32585080    3.05952602   -0.36501626
 H                 -1.22806234   -1.87910107   -0.66356524
 H                 -0.31728479   -3.06721975    0.33088624

C H O 0
6-31G*
****


