%nprocshared=20
%mem=41GB
#p opt=(calcfc,maxstep=9) freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  1.00454341   -3.58501414    0.66551930
 H                  0.33801692   -4.40334102    0.37761295
 H                  2.04286665   -3.92445069    0.55045066
 H                  0.82875511   -3.34803954    1.72439060
 C                  3.60431772   -0.90428916   -0.68104779
 H                  3.95127834   -1.93338913   -0.54948953
 H                  3.28745465   -0.77351920   -1.72535892
 H                  4.44475613   -0.22524744   -0.48264476
 C                  2.59325339    2.66229535    0.64750865
 H                  3.65248631    2.44690852    0.47899205
 H                  2.42022746    3.73008830    0.45625715
 H                  2.35771510    2.45226461    1.70041085
 C                 -1.01174871    3.57797708   -0.65415392
 H                 -2.02868028    3.95895706   -0.48909533
 H                 -0.30388861    4.39580412   -0.49014423
 H                 -0.92675919    3.24729034   -1.69898244
 C                 -3.61114317    0.88833420    0.66856148
 H                 -3.95802607    1.91808085    0.54193104
 H                 -4.45091154    0.21023077    0.46425393
 H                 -3.29684477    0.75177570    1.71291017
 C                 -2.59028385   -2.66835156   -0.69285552
 H                 -2.34073836   -2.44774402   -1.74036753
 H                 -2.41933630   -3.73793539   -0.51001770
 H                 -3.65179349   -2.45501914   -0.53648156
 O                 -1.84634122   -1.86284129    0.21901306
 H                 -0.88084574   -2.04820554    0.05474291
 O                 -2.53955490    0.67496229   -0.24807384
 H                 -2.20787163   -0.25317803   -0.09978144
 O                 -0.69361774    2.53685723    0.26743098
 H                 -1.33339949    1.79118927    0.09906838
 O                  1.83683632    1.84802543   -0.24615670
 H                  0.87361721    2.03381043   -0.06941881
 O                  2.53504238   -0.68549297    0.23702741
 H                  2.20222763    0.24138028    0.08341997
 O                  0.72523958   -2.47669801   -0.18765023
 H                  1.32522575   -1.73192313    0.09342298

C H O 0
6-31G*
****






