%nprocshared=20
%mem=41GB
#p opt freq=noraman scrf=(solvent=dichloromethane,pcm) nosymm b3lyp gen empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  1.06673558    2.75230421   -0.77569542
 H                  1.94791125    2.48619580   -0.18160891
 H                  0.12061172    0.89140725   -1.30564223
 O                  0.10093791   -0.79781625   -1.85983639
 C                 -1.08703819   -1.18259843   -2.59411355
 H                 -1.07568384   -2.25553876   -2.80551759
 O                  0.07456478    1.70495019   -0.74440311
 H                 -1.16143833   -0.61452926   -3.52585472
 H                 -1.93397324   -0.94536104   -1.94922146
 H                  0.63227692    3.68283180   -0.39971621
 H                  1.35659260    2.88335128   -1.81926838
 H                  0.14202669   -1.51752280   -0.23058411
 O                  0.08740191   -1.65938619    0.74633637
 C                  1.25445883   -2.38050999    1.18958530
 H                  2.17699772   -1.84123385    0.94536888
 H                  1.27444721   -3.37285397    0.72966386
 H                  1.17128624   -2.48667386    2.27239767
 H                 -0.06523032   -0.31735634    1.29042158
 O                 -0.15562417    0.71174985    1.52503068
 C                 -1.32826010    0.81089052    2.38941409
 H                 -0.09365173    1.21120553    0.58298760
 H                 -2.19022630    0.33186671    1.91849404
 H                 -1.51697109    1.87061992    2.55808656
 H                 -1.07859559    0.31709300    3.32783050

C H O 0
6-31G*
****







