%nprocshared=20
%mem=41GB
#p opt freq=noraman scrf=(solvent=dichloromethane,pcm) nosymm b3lyp gen empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                 -0.13073539    1.87493255   -2.29328023
 H                 -1.12626338    1.43861761   -2.43030685
 H                  0.66710918    0.30207238   -1.34107223
 O                  0.57046085   -1.46792946   -1.20415324
 C                 -0.33164826   -2.10169357   -2.14386048
 H                 -0.42012765   -3.17023749   -1.92843801
 O                  0.55960367    1.27213595   -1.17864990
 H                  0.01658596   -1.95047331   -3.16965038
 H                 -1.30046848   -1.61942242   -2.00870025
 H                  0.45960046    1.74732811   -3.20499126
 H                 -0.22641845    2.93838601   -2.06934614
 H                 -0.07655960   -1.48047558    0.45576722
 O                 -0.49103357   -1.22148140    1.31519496
 C                  0.31530593   -1.71787121    2.40235861
 H                  1.33902966   -1.32908416    2.35364737
 H                  0.33457481   -2.81141751    2.38093428
 H                 -0.15675488   -1.38372894    3.32765781
 H                 -0.60582215    0.22762102    1.22978303
 O                 -0.60546673    1.26593611    1.01960763
 C                  0.15002123    2.00843105    2.02459609
 H                 -0.13880174    1.34880893    0.06247776
 H                  1.19073408    1.67550481    2.04168717
 H                 -0.33026381    1.83122466    2.98637196
 H                  0.08767125    3.06319342    1.75929903

C H O 0
6-31G*
****








