%nprocshared=20
%mem=41GB
#p opt freq=noraman scrf=(solvent=dichloromethane,pcm) nosymm b3lyp gen empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  2.18338582    0.18657759    1.59732918
 H                  1.68364208    1.03831680    1.10900256
 H                  0.78611059   -1.14303812    1.33960520
 O                 -0.40494608   -0.83526993   -0.34381907
 C                 -1.13914570   -1.99513656   -0.85958298
 H                 -1.64446888   -2.45310764   -0.01075072
 O                  1.25616450   -0.76880654    2.10293670
 H                 -0.40240833   -2.67586241   -1.28310515
 H                 -1.85623099   -1.67083122   -1.61637794
 H                  2.89157132   -0.25880231    0.88285756
 H                  2.74984882    0.56999356    2.44992418
 H                 -1.06891474   -0.14173282    0.13221913
 O                 -1.95056276    0.63415623    0.90148879
 C                 -1.33916939    1.30149295    2.03776693
 H                 -0.83390980    2.21936660    1.72221536
 H                 -0.60964631    0.59788508    2.44107887
 H                 -2.10791183    1.52852762    2.78017194
 H                  0.15617691   -0.37322087   -1.11181466
 O                  0.90792376    0.16453893   -2.21674895
 C                  0.25299343    1.22822294   -2.94664814
 H                  1.80156689    0.44695021   -1.95803230
 H                  0.15125442    2.12648411   -2.32953082
 H                 -0.73338215    0.85008407   -3.21866825
 H                  0.81968170    1.45509631   -3.85284470

C H O 0
6-31G*
****



