%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                 -0.02560441   -3.69130900    0.33106999
 H                  0.27781558   -3.28495037    1.30134956
 H                 -0.58246711   -1.62996607   -0.42882964
 O                 -0.07103232   -0.56771760   -0.70286581
 C                  1.12637696   -0.80074560   -1.56592030
 H                  1.22161328    0.07834721   -2.21142489
 O                 -1.02405800   -2.73439817   -0.23762933
 H                  0.90697139   -1.67489470   -2.14265640
 H                  1.97584205   -0.90034138   -0.92296635
 H                  0.79624584   -3.69796495   -0.35407079
 H                 -0.51069654   -4.63825254    0.44457583
 H                 -0.18001874    0.05920609    0.01594478
 O                 -0.30370722    0.86393873    0.90388447
 C                  0.53094218    0.56426943    2.10786348
 H                  1.57468481    0.59421342    1.77871593
 H                  0.25587003   -0.42275763    2.41610511
 H                  0.33481111    1.32282000    2.83658401
 H                 -0.13090262    1.75304517    0.58572049
 O                  0.10806660    2.86930152    0.20075835
 C                 -0.53517293    3.20531595   -1.10666047
 H                 -0.12893196    3.52925277    0.87996947
 H                 -1.61632805    3.13521511   -0.94910752
 H                 -0.20074042    2.45963722   -1.79732546
 H                 -0.24717196    4.20321004   -1.36388181

C H O 0
6-31G*
****














