%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                 -0.93733380   -3.45868768    1.83742244
 H                 -0.10946878   -2.95709109    2.34896309
 H                 -1.41285105   -1.59232910    0.64273955
 O                 -0.92864628   -0.88237535   -0.20963630
 C                 -1.87592679   -0.50400364   -1.30162923
 H                 -2.67447271    0.08048613   -0.83339165
 O                 -1.88890708   -2.38557700    1.41439929
 H                 -2.25650256   -1.42459109   -1.69224518
 H                 -1.33406132    0.08426719   -2.01241702
 H                 -0.60206156   -3.92482445    0.93453316
 H                 -1.46060994   -4.11390156    2.50208542
 H                 -0.53465761   -0.09925856    0.18164498
 O                 -0.03319497    0.89160119    0.64861664
 C                  1.22913838    0.62744170    1.40541321
 H                  1.93996671    0.20492169    0.68789430
 H                  0.97443647   -0.08934735    2.15790267
 H                  1.57956745    1.56246161    1.78990928
 H                  0.11261743    1.55358451   -0.03117512
 O                  0.32156889    2.38055074   -0.88193743
 C                  0.04405761    3.78180962   -0.43982000
 H                  1.23182838    2.30270888   -1.22603047
 H                  0.72461237    3.98629468    0.39304526
 H                 -0.97427341    3.78859882   -0.11140589
 H                  0.24298823    4.42956300   -1.26791551

C H O 0
6-31G*
****










