%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  1.28488776   -3.22838598   -0.86110494
 H                  2.02367577   -2.42049564   -0.87289228
 H                 -0.27981965   -1.86909145    0.05578510
 O                 -0.92864628   -0.88237535   -0.20963630
 C                 -2.37355012   -0.98290758    0.15792353
 H                 -2.41177983   -1.09097957    1.24668854
 O                  0.31501003   -2.90224288    0.22929622
 H                 -2.73881045   -1.86482584   -0.32550700
 H                 -2.85239321   -0.07916275   -0.15648799
 H                  0.71473009   -3.23774804   -1.76649579
 H                  1.74220817   -4.16524021   -0.62014392
 H                 -0.53465761   -0.09925856    0.18164498
 O                 -0.03319497    0.89160119    0.64861664
 C                  1.22913838    0.62744170    1.40541321
 H                  1.93996671    0.20492169    0.68789430
 H                  0.97443647   -0.08934735    2.15790267
 H                  1.57956745    1.56246161    1.78990928
 H                  0.11261743    1.55358451   -0.03117512
 O                  0.32156889    2.38055074   -0.88193743
 C                  0.04405761    3.78180962   -0.43982000
 H                  1.23182838    2.30270888   -1.22603047
 H                  0.72461237    3.98629468    0.39304526
 H                 -0.97427341    3.78859882   -0.11140589
 H                  0.24298823    4.42956300   -1.26791551

C H O 0
6-31G*
****








