%nprocshared=20
%mem=41GB
#p opt freq=noraman b3lyp gen scrf=(solvent=dichloromethane,pcm) nosymm empiricaldispersion=gd3 scf=(xqc,maxcyc=512)

opt freq

0 1
 C                  1.81039976   -1.77454488    0.25180291
 H                  1.85126696   -1.23438393   -0.70823134
 H                  0.28661939   -0.83351773    1.01248059
 O                 -1.01864411   -0.04706827    0.09281933
 C                 -1.97456702    0.52786362    0.98287523
 H                 -1.49543938    1.03284924    1.83360132
 O                  1.21860697   -1.00448077    1.28463313
 H                 -2.59791426   -0.28441432    1.36699430
 H                 -2.62210663    1.24991105    0.46618975
 H                  1.28457167   -2.72775655    0.08267299
 H                  2.83865175   -2.00446830    0.55115838
 H                 -0.36492379    0.64657266   -0.16417557
 O                  0.99118684    1.70269807    0.17079558
 C                  1.92296356    2.17248138   -0.81621586
 H                  1.26150170    0.98387756    0.76313496
 H                  1.58886203    3.11292610   -1.27311755
 H                  1.96559252    1.40267845   -1.58963033
 H                  2.91938879    2.31762783   -0.38040923

C H O 0
6-31G*
****







